Synthesis of a ceramide sphingolipid as a potential sex pheromone of the hair crab Erimacrus isenbeckii using butane-2,3-diacetal desymmetrised glycolic acid building blocks

被引：21

作者：

Dixon, DJ ^{[1
]}

Ley, SV ^{[1
]}

Lohmann, S ^{[1
]}

Sheppard, TD ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

SYNLETT | 2005年 / 03期

关键词：

acetals; chiral auxiliaries; pheromones; sphingolipids; stereoselective synthesis;

D O I：

10.1055/s-2005-862361

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A stereoselective synthesis of a ceramide sphingolipid as a potential sex pheromone of the hair crab Erimacrus isenbeckii is reported using diastereoselective alkylation and aldol reactions of butane-2,3-diacetal (BDA) desymmetrised glycolic acid building blocks as the key synthetic steps.

引用

页码：481 / 484

页数：4

共 24 条

[1] Sex pheromones of the hair crab EP Erimacrus isenbeckii.: Part 1:: Isolation and structures of novel ceramides [J].