Novel clay treatment and preparation of poly(ethylene terephthalate)/clay nanocomposite by in-situ polymerization

被引:22
作者
Kim, SH
Park, SH
Kim, SC
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem & Biomol Engn, Ctr Adv Funct Polymers, Taejon 305701, South Korea
[2] Honam Petrochem Corp, Daeduk Res Inst, Taejon 305726, South Korea
关键词
D O I
10.1007/s00289-005-0339-8
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Novel clay treatment was proposed for poly(ethylene terephthalate) (PET)/clay nanocomposite and the clay dispersed trimellitate ester oligomers were prepared by esterification with 1, 2, 4-Benzenetricarboxylic anhydride (TMA, trimellitic anhydride) and montmorillonite (MMT) dispersed ethylene glycol (EG). The structure, interlayer distance and thermal stability of the clay dispersed trimellitate ester oligomers were investigated by NMR, WAXD, SAXS and TGA techniques.
引用
收藏
页码:285 / 292
页数:8
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