Properties and applications of trinuclear ruthenium carboxylate clusters.

被引：16

作者：

Alexiou, ADP ^{[1
]}

Dovidauskas, S ^{[1
]}

Toma, HE ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim, BR-05513970 Sao Paulo, Brazil

来源：

QUIMICA NOVA | 2000年 / 23卷 / 06期

关键词：

ruthenium-acetate clusters; oxo-ruthenium clusters; ruthenium-carboxylated clusters; catalysis;

D O I：

10.1590/S0100-40422000000600012

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A review with 94 references focusing on mu (3)-oxo-triruthenium carboxylate clusters is presented. The electronic, magnetic, electrochemical, and catalytic properties of these compounds are discussed. Main synthetic routes and structural characteristics, including their use as building blocks in supramolecular systems are described.

引用

页码：785 / 793

页数：9

共 94 条

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[2] REVERSIBLE MULTISTEP AND MULTIELECTRON REDOX BEHAVIOR OF AN OXO-CENTERED TRINUCLEAR RUTHENIUM COMPLEX WITH A REDOX-ACTIVE LIGAND, [RU-3(MU(3)-O)(MU-CH3CO2)(6)(MBPY(+))(3)](4+)(MBPY(+)=N-METHYL-4,4'-BIPYRIDINIUM ION), AND ITS TRIRHODIUM AND DIRUTHENIUM-RHODIUM DERIVATIVES
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ITO, T
[J]. INORGANIC CHEMISTRY, 1995, 34 (17) : 4490 - 4498
[3] KINETIC-STUDIES ON THE TERMINAL PYRIDINE EXCHANGE-REACTIONS OF SOME OXO-ACETATE BRIDGED TRINUCLEAR RUTHENIUM COMPLEXES - INFLUENCE OF THE METAL OXIDATION-STATE AND NON-LEAVING TERMINAL LIGAND (CO)
ABE, M
SASAKI, Y
NAGASAWA, A
ITO, T
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1992, 65 (05) : 1411 - 1414
[4] Oxo-centered mixed-ligand triruthenium complexes having redox-active N-methyl-4,4'-bipyridinium ions (mbpy(+)). Reversible multistep electrochemical properties of [RuIII2RuII(mu(3)-O)(mu-CH3CO2)(6)(mbpy(+))(2)(CO)](2+) and [RuIII3(mu(3)-O)(mu-CH3CO2)(6)(mbpy(+))(2)(L)](3+) (L=H2O and n-heterocyclic ligands)
Abe, M
Sasaki, Y
Yamada, Y
Tsukahara, K
Yano, S
Yamaguchi, T
Tominaga, M
Taniguchi, I
Ito, T
[J]. INORGANIC CHEMISTRY, 1996, 35 (23) : 6724 - 6734
[5] X-RAY STRUCTURE, LIGAND SUBSTITUTION, AND OTHER PROPERTIES OF TRINUCLEAR RUTHENIUM COMPLEX, [RU3(MU-3-O)(MU-C6H5COO)6(PY)3](PF6) (PY=PYRIDINE), AND X-RAY STRUCTURE OF DINUCLEAR RUTHENIUM COMPLEX, [RU2(MU-C6H5COO)4CL]
ABE, M
SASAKI, Y
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ITO, T
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1992, 65 (06) : 1585 - 1590
[6] PREPARATION AND ELECTROCHEMICAL RESPONSE OF POLY(4-VINYLPYRIDINE)-COORDINATED OXO-ACETATO TRIRUTHENIUM CLUSTER FILM
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[7] ALEXIOU ADP, 1993, J CHEM RES, P464
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[J]. JOURNAL OF CHEMICAL RESEARCH-S, 1997, (09): : 338 - 339
[9] ALEXIOU ADP, 1993, THESIS U SAO PAULO S
[10] THE STRUCTURE OF OXO-BRIDGED TRINUCLEAR RUTHENIUM AND IRIDIUM HEXACARBOXYLATES
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