Crystallochemical and magnetic studies of LiM1-xMx'PO4 (M, M′ = Mn, Co, Ni; O≤x≤1)

被引：14

作者：

Rissouli, K

Benkhouja, K

Bettach, M

Sadel, A

Zahir, M

Derrory, A

Drillon, M

机构：

[1] Univ Chouaib Doukkali, Fac Sci, LPCM, Dept Chim, El Jadida 24000, Morocco

[2] GMI, LPCMS, F-67037 Strasbourg, France

来源：

ANNALES DE CHIMIE-SCIENCE DES MATERIAUX | 1998年 / 23卷 / 1-2期

关键词：

D O I：

10.1016/S0151-9107(98)80029-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A crystallochemical study of the mixed orthophosphates LiM1-xMx'PO4 (M, M'= Mn, Co, Ni; 0 less than or equal to x less than or equal to 1) using X-ray diffraction, shows that the three systems are isostructural to olivine. The results of the magnetic susceptibility and specific heat of Li(Mn,Co)(0.5)PO4, Li(Mn,Ni)(0.5)PO4 and Li(Co,Ni)(0.5)PO4 exhibit an antiferromagnetic behaviour at low temperature.

引用

页码：85 / 88

页数：4

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