Cu-Catalyzed Oxidative Amidation of Propiolic Acids Under Air via Decarboxylative Coupling

被引：229
|
作者：
Jia, Wei [1 ]
Jiao, Ning [1 ,2 ]
机构：
[1] Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100083, Peoples R China
[2] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
来源：
ORGANIC LETTERS | 2010年 / 12卷 / 09期
基金：
美国国家科学基金会;
关键词：
PAUSON-KHAND REACTIONS; ALKYNYL BROMIDES; CARBOXYLIC-ACIDS; STEREOSELECTIVE-SYNTHESIS; SUBSTITUTED YNAMIDES; SONOGASHIRA REACTION; ALLYLIC ALKYLATIONS; EFFICIENT SYNTHESIS; MOLECULAR-OXYGEN; N-ALKYNYLATION;
D O I：
10.1021/ol1004615
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A Cu-catalyzed aerobic oxidative amidation of propiolic acids via decarboxylation under air has been developed. Only carbon dioxide is produced as byproduct in this approach. The use of air as oxidant makes this method more useful and easy to handle.
引用
收藏
页码：2000 / 2003
页数：4
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