Remote-controlled experiments with cloud chemistry

被引：54

作者：

Skilton, Ryan A. ^{[1
]}

Bourne, Richard A. ^{[1
]}

Amara, Zacharias ^{[1
]}

Horvath, Raphael ^{[1
]}

Jin, Jing ^{[1
]}

Scully, Michael J. ^{[2
]}

Streng, Emilia ^{[1
]}

Tang, Samantha L. Y. ^{[1
]}

Summers, Peter A. ^{[3
]}

Wang, Jiawei ^{[3
]}

Perez, Eduardo ^{[4
]}

Asfaw, Nigist ^{[4
]}

Aydos, Guilherme L. P. ^{[5
]}

Dupont, Jairton ^{[1
,5
]}

Comak, Gurbuz ^{[6
]}

George, Michael W. ^{[1
,3
]}

Poliakoff, Martyn ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[2] Univ Nottingham, Informat Serv, Nottingham NG7 2NR, England

[3] Univ Nottingham Ningbo China, Dept Chem & Environm Engn, Ningbo 315100, Zhejiang, Peoples R China

[4] Univ Addis Ababa, Dept Chem, Addis Ababa, Ethiopia

[5] Univ Fed Rio Grande do Sul, Inst Chem, BR-91501970 Porto Alegre, RS, Brazil

[6] Petkim Petrochem Holding, R&D & Qual Assurance Dept, TR-35800 Izmir, Turkey

来源：

NATURE CHEMISTRY | 2015年 / 7卷 / 01期

关键词：

SUPERCRITICAL CARBON-DIOXIDE; DIMETHYL CARBONATE; SELF-OPTIMIZATION; CO2; ALCOHOLS; CLEANER; SYSTEMS; FLUIDS;

D O I：

10.1038/nchem.2143

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Developing cleaner chemical processes often involves sophisticated flow-chemistry equipment that is not available in many economically developing countries. For reactions where it is the data that are important rather than the physical product, the networking of chemists across the internet to allow remote experimentation offers a viable solution to this problem.

引用

页码：1 / 5

页数：5

共 18 条

[1] Continuous reactions in supercritical fluids;: a cleaner, more selective synthesis of thymol in supercritical CO2 [J].

Amandi, R ;

Hyde, JR ;

Ross, SK ;

Lotz, TJ ;

Poliakoff, M .

GREEN CHEMISTRY, 2005, 7 (05) :288-293

[2] The synthesis of o-cyclohexylphenol in supercritical carbon dioxide:: towards a continuous two-step reaction [J].

Amandi, Rodrigo ;

Scovell, Katherine ;

Licence, Peter ;

Lotz, Tobias J. ;

Poliakoff, Martyn .

GREEN CHEMISTRY, 2007, 9 (07) :797-801

[3] Adaptive Process Optimization for Continuous Methylation of Alcohols in Supercritical Carbon Dioxide [J].

Bourne, Richard A. ;

Skilton, Ryan A. ;

Parrott, Andrew J. ;

Irvine, Derek J. ;

Poliakoff, Martyn .

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2011, 15 (04) :932-938

[4] Continuous Acid-Catalyzed Methylations in Supercritical Carbon Dioxide: Comparison of Methanol, Dimethyl Ether and Dimethyl Carbonate as Methylating Agents [J].

Gooden, Peter N. ;

Bourne, Richard A. ;

Parrott, Andrew J. ;

Bevinakatti, Han S. ;

Irvine, Derek J. ;

Poliakoff, Martyn .

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2010, 14 (02) :411-416

[5] The continuous acid-catalyzed dehydration of alcohols in supercritical fluids: a new approach to the cleaner synthesis of acetals, ketals, and ethers with high selectivity [J].

Gray, WK ;

Smail, FR ;

Hitzler, MG ;

Ross, SK ;

Poliakoff, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (46) :10711-10718

[6] Continuous reactions in supercritical carbon dioxide: problems, solutions and possible ways forward [J].

Han, Xue ;

Poliakoff, Martyn .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (04) :1428-1436

[7] Continuous hydrogenation reactions in supercritical CO2 "without gases'' [J].

Hyde, JR ;

Walsh, B ;

Singh, J ;

Poliakoff, M .

GREEN CHEMISTRY, 2005, 7 (05) :357-361

[8] The Effect of Self-Optimisation Targets on the Methylation of Alcohols Using Dimethyl Carbonate in Supercritical CO2 [J].

Jumbam, Denis N. ;

Skilton, Ryan A. ;

Parrott, Andrew J. ;

Bourne, Richard A. ;

Poliakoff, Martyn .

JOURNAL OF FLOW CHEMISTRY, 2012, 2 (01) :24-27

[9]

Krishnadasan S, 2007, LAB CHIP, V7, P1434, DOI 10.1039/b711412e

[10] Selective monoprotection of 1,n-terminal Diols in Supercritical carbon dioxide:: A striking example of solvent tunable desymmetrization [J].

Licence, P ;

Gray, WK ;

Sokolova, M ;

Poliakoff, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (01) :293-298

← 1 2 →