REMOVAL OF CRYSTAL VIOLET DYE FROM AQUEOUS SOLUTION BY GAMMA IRRADIATION

被引:30
作者
Rehman, Faiza [1 ]
Sayed, Murtaza [1 ]
Khan, Javed Ali [1 ]
Khan, Hasan M. [1 ]
机构
[1] Univ Peshawar, Natl Ctr Excellence Phys Chem, Radiat & Environm Chem Lab, Peshawar 25120, Pakistan
关键词
Crystal violet dye; gamma irradiation; 'OH-radicals; removal efficiency; WASTE-WATER; TEXTILE DYES; DEGRADATION; OXIDATION; DECOLORIZATION; POLLUTANTS;
D O I
10.4067/S0717-97072017000100011
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study the radiation-induced degradation of crystal violet ( CV) dye under various experimental conditions has been investigated. D-0.5, D-0.9 and D-0.99 values suggests that lower doses are required for 50%, 90% and 99% removal of CV dye when the sample solution contains excessive amount of 'OH radicals. The removal efficiency of CV dye in terms of G-values was also calculated under each reaction conditions. The results showed that 'OH radicals are playing effective role in the degradation of CV dye as compared to e(aq)(-) and 'H radicals. The gamma irradiation process effectively degraded CV dye at all pH values. The organic byproducts were examined and accordingly degradation pathway was proposed.
引用
收藏
页码:3359 / 3364
页数:6
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