Adsorption kinetics of potassium on SrTiO3(100)

被引：5
作者：
Mori, E. E. [1 ]
Kamaratos, M. [1 ]
机构：
[1] Univ Ioannina, Dept Phys, GR-45110 Ioannina, Greece
来源：
SURFACE REVIEW AND LETTERS | 2006年 / 13卷 / 05期
关键词：
potassium; strontium titanate; adsorption; AES; WF; EELS; TPD; ELECTRONIC-STRUCTURE; CS; FILMS; TIO2; OXIDATION; W(110); OXYGEN; STATES; STEPS; O-2;
D O I：
10.1142/S0218625X06008657
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this paper, we study the kinetics of potassium adsorption on SrTiO3(100) surface at room temperature. The study took place in UHV using AES, EELS, LEED, TPD, and WF measurements. Potassium grows in two-dimensional islands with maximum coverage of 3.9 X 10(14) at/cm(2). During adsorption charge transfer from the K-4s to Ti-3d energy level has been observed. No K-O compound has been measured. After heating at 1050 K most of the adsorbed potassium desorbs and the SrTiO3(100) (1 x 1) LEED pattern reappears. There is not any indication of potassium intercalation into the substrate, either at room or at elevated temperature.
引用
收藏
页码：681 / 686
页数：6
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