Manganese(III) Acetate Mediated C-H Sulfonylation of 1,4-Dimethoxybenzenes with Sodium and Lithium Sulfinates

被引：18

作者：

Liang, Shuai ^{[1
]}

Ren, Yueling ^{[1
]}

Manolikakes, Georg ^{[1
]}

机构：

[1] Goethe Univ Frankfurt, Inst Organ Chem & Chem Biol, Max von Laue Str 7, D-60438 Frankfurt, Germany

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 2017卷 / 28期

关键词：

Earth-abundant metals; Sulfur; C-H activation; Manganese; Dehydrogenation; Sulfinic acid; Cross-coupling; QUINOLINE N-OXIDES; SULFUR-DIOXIDE; DIARYLIODONIUM SALTS; DIARYL SULFONES; ARYL SULFONES; ACID SALTS; CATALYZED SULFONYLATION; BOND FUNCTIONALIZATION; AROMATIC-COMPOUNDS; C(SP(2))-H BONDS;

D O I：

10.1002/ejoc.201700713

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and mild Mn(OAc)(3)-promoted oxidative coupling of 1,4-dimethoxybenzenes with sodium and lithium sulfinates was developed. The reaction proceeded readily at room temperature in air, and various sulfones were synthesized in moderate to high yields. In addition, a straightforward approach for the conversion of organolithium reagents and sulfur dioxide into sulfonylated 1,4-dimethoxybenzenes was explored.

引用

页码：4117 / 4120

页数：4

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