Bis[μ2-bis(diphenylphosphino)methane]-1:2κ2P:P′;2:3κ2P:P′-dichlorido-1κCl,3κCl-triangulo-trigold(I) hexafluorophosphate

被引：2

作者：

Constable, Edwin C. ^{[1
]}

Housecroft, Catherine E. ^{[1
]}

Neuburger, Markus ^{[1
]}

Schaffner, Silvia ^{[1
]}

Shardlow, Ellen J. ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

D O I：

10.1107/S160053680702421X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Au3Cl2(C25H22P2)(2)](PF6), the cation possesses a triangular Au-3 core [Au-Au distances 3.1525 (4), 3.2770 (4) and 3.1922 (4) angstrom], two sides of which are bridged by dppm ligands [dppm = bis(diphenylphosphino) methane]. One phenyl group is disordered over two positions in a 0.65:0.35 ratio. The structure of the cation is compared with those in three other salts reported previously.

引用

页码：M1698 / U1084

页数：16

共 14 条

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