Cyclopentadiene-mediated hydride transfer from rhodium complexes

被引：150

作者：

Pitman, C. L. ^{[1
]}

Finster, O. N. L. ^{[1
]}

Miller, A. J. M. ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 58期

基金：

美国国家科学基金会;

关键词：

1,4-NADH DERIVATIVES; ORGANIC-SYNTHESIS; REDUCTION; REGENERATION; CATALYSTS; WATER; REACTIVITY; HYDRICITY; CHEMISTRY; COFACTORS;

D O I：

10.1039/c6cc00575f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Attempts to generate a proposed rhodium hydride catalytic intermediate instead resulted in isolation of (Cp*H)Rh(bpy)Cl (1), a pentamethylcyclopentadiene complex, formed by C-H bond-forming reductive elimination from the fleeting rhodium hydride. The hydride transfer ability of diene 1 was explored through thermochemistry and hydride transfer reactions, including the reduction of NAD(+).

引用

页码：9105 / 9108

页数：4

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