Poly[bis(μ-4-benzoyl-1-isonicotinoylthiosemicarbazide-κ2N:S)dichloridocadmium(II)]

被引：6

作者：

Wang, Yu-Bo ^{[1
]}

Pan, Tong-Hen ^{[1
]}

Liang, Qian ^{[1
]}

Liu, Dong-Sheng ^{[1
,2
]}

Huang, Chang-Cang ^{[1
]}

机构：

[1] Fuzhou Univ, Coll Chem & Chem Engn, State Key Lab Breeding Base Photocatalysis, Fuzhou 350108, Fujian, Peoples R China

[2] Jinggangshan Univ, Coll Chem & Chem Engn, Jian 343009, Jiangxi, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2010年 / 66卷

关键词：

COMPLEXES; THIOSEMICARBAZIDE;

D O I：

10.1107/S0108270110011455

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The asymmetric unit of the title complex, [CdCl2(C14H12N4O2S)(2)](n), consists of one Cd-II ion located on the crystallographic inversion centre, one 4-benzoyl-1-isonicotinoylthiosemicarbazide ligand and one chloride ligand. The central Cd-II ion adopts a distorted octahedral coordination geometry formed by two pyridyl N atoms of two ligands, two S atoms of two other ligands and two chloride ligands. The thiosemicarbazide ligands act as bridges, linking the metal ions into a two-dimensional layered structure parallel to the bc plane. Intermolecular N-H center dot center dot center dot O hydrogen bonds and C-H center dot center dot center dot pi interactions exist between adjacent layers.

引用

页码：M127 / M129

页数：3

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