Cross-linked polymer networks based on polysiloxane and nickel β-diketonate precursors

被引：9

作者：

Kim, E. E. ^{[1
]}

Kononevich, Yu. N. ^{[1
]}

Anisimov, A. A. ^{[1
]}

Buzin, M. I. ^{[1
]}

Vasil'ev, V. G. ^{[1
]}

Korlyukov, A. A. ^{[1
,2
]}

Ionov, D. S. ^{[3
]}

Khanin, D. A. ^{[1
]}

Shtykova, E. V. ^{[4
]}

Volkov, V. V. ^{[4
]}

Muzafarov, A. M. ^{[1
,5
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[2] Pirogov Russian Natl Res Med Univ, Moscow 117997, Russia

[3] Russian Acad Sci, FSRC Crystallog & Photon, Photochem Ctr, Moscow 119421, Russia

[4] Russian Acad Sci, Fed Sci Res Ctr Crystallog & Photon, Shubnikov Inst Crystallog, Moscow 119333, Russia

[5] Russian Acad Sci, NS Enikolopov Inst Synthet Polymer Mat, Moscow 117393, Russia

来源：

REACTIVE & FUNCTIONAL POLYMERS | 2021年 / 164卷 / 164期

基金：

俄罗斯科学基金会;

关键词：

Polysiloxanes; Cross-linked polymers; Metal-ligand interaction; Nickel beta-diketonates; Mechanical properties; CHAIN HYDROCARBON SUBSTITUENTS; SMALL-ANGLE SCATTERING; RHEOLOGICAL PROPERTIES; COORDINATION POLYMERS; MAGNETIC-PROPERTIES; THERMAL-PROPERTIES; HIGH TOUGHNESS; HYDROGELS; COMPLEXES; LINKING;

D O I：

10.1016/j.reactfunctpolym.2021.104896

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Elastic cross-linked by metal-ligand interaction networks based on polysiloxanes have attracted wide attention in the field of materials science as materials with self-healing, shape-memory and recyclable elastomeric properties. A series of novel cross-linked polymers based on linear polysiloxane and metal beta-diketonate precursors by the reaction of multiligand PDMS with grafted beta-diketonate fragments and Nickel (II) acetate have been successfully prepared and fully characterized. Physicochemical, mechanical, rheological and thermal properties of all polymers are studied. The proposed approach to preparation coordination polysiloxane polymers can be usefully utilized at the design and development of new smart materials with unique properties and easy recyclability.

引用

页数：14

共 69 条

[1] Organoelement chemistry: promising growth areas and challenges [J].

Abakumov, Gleb A. ;

Piskunov, Alexandr V. ;

Cherkasov, Vladimir K. ;

Fedushkin, Igor L. ;

Ananikov, Valentine P. ;

Eremin, Dmitry B. ;

Gordeev, Evgeniy G. ;

Beletskaya, Irina P. ;

Averin, Alexei D. ;

Bochkarev, Mikhail N. ;

Trifonov, Alexander A. ;

Dzhemilev, Usein M. ;

D'yakonov, Vladimir A. ;

Egorov, Mikhail P. ;

Vereshchagin, Anatoly N. ;

Syroeshkin, Mikhail A. ;

Jouikov, Viatcheslav V. ;

Muzafarov, Aziz M. ;

Anisimov, Anton A. ;

Arzumanyan, Ashot V. ;

Kononevich, Yuriy N. ;

Temnikov, Maxim N. ;

Sinyashin, Oleg G. ;

Budnikova, Yulia H. ;

Burilov, Alexander R. ;

Karasik, Andrey A. ;

Mironov, Vladimir F. ;

Storozhenko, Pavel A. ;

Shcherbakova, Galina I. ;

Trofimov, Boris A. ;

Amosova, Svetlana V. ;

Gusarova, Nina K. ;

Potapov, Vladimir A. ;

Shur, Vladimir B. ;

Burlakov, Vladimir V. ;

Bogdanov, Vyacheslav S. ;

Andreev, Maxim V. .

RUSSIAN CHEMICAL REVIEWS, 2018, 87 (05) :393-507

[2] Syntheses, Structures, and Magnetic Properties of a Family of Tetranuclear Hydroxido-Bridged Ni2IILn2III (Ln = La, Gd, Tb, and Dy) Complexes: Display of Slow Magnetic Relaxation by the Zinc(II)-Dysprosium(III) Analogue [J].

Abtab, Sk Md Towsif ;

Maity, Manoranjan ;

Bhattacharya, Kisholoy ;

Sanudo, E. Carolina ;

Chaudhury, Muktimoy .

INORGANIC CHEMISTRY, 2012, 51 (19) :10211-10221

[3]

Barnes H.A., 2000, A Handbook of Elementary Rheology

[4] Optically healable supramolecular polymers [J].

Burnworth, Mark ;

Tang, Liming ;

Kumpfer, Justin R. ;

Duncan, Andrew J. ;

Beyer, Frederick L. ;

Fiore, Gina L. ;

Rowan, Stuart J. ;

Weder, Christoph .

NATURE, 2011, 472 (7343) :334-U230

[5] Dipyridyl β-diketonate complexes and their use as metalloligands in the formation of mixed-metal coordination networks [J].

Burrows, Andrew D. ;

Mahon, Mary F. ;

Renouf, Catherine L. ;

Richardson, Christopher ;

Warren, Anna J. ;

Warren, John E. .

DALTON TRANSACTIONS, 2012, 41 (14) :4153-4163

[6] Polydimethylsiloxane thermal degradation - Part 1. Kinetic aspects [J].

Camino, G ;

Lomakin, SM ;

Lazzari, M .

POLYMER, 2001, 42 (06) :2395-2402

[7] Difluoroboron β-diketonate dyes: Spectroscopic properties and applications [J].

Chen, Peng-Zhong ;

Niu, Li-Ya ;

Chen, Yu-Zhe ;

Yang, Qing-Zheng .

COORDINATION CHEMISTRY REVIEWS, 2017, 350 :196-216

[8] Investigating the effect of ligand and cation on the properties of metal fluorinated acetylacetonate based magnetic ionic liquids [J].

Farooq, Muhammad Qamar ;

Chand, Deepak ;

Odugbesi, Gabriel A. ;

Varona, Marcelino ;

Mudryk, Yaroslav ;

Anderson, Jared L. .

NEW JOURNAL OF CHEMISTRY, 2019, 43 (28) :11334-11341

[9] Making hybrid [n]-rotaxanes as supramolecular arrays of molecular electron spin qubits [J].

Fernandez, Antonio ;

Ferrando-Soria, Jesus ;

Pineda, Eufemio Moreno ;

Tuna, Floriana ;

Vitorica-Yrezabal, Inigo J. ;

Knappke, Christiane ;

Ujma, Jakub ;

Muryn, Christopher A. ;

Timco, Grigore A. ;

Barran, Perdita E. ;

Ardavan, Arzhang ;

Winpenny, Richard E. P. .

NATURE COMMUNICATIONS, 2016, 7

[10] Toughening elastomers using mussel-inspired iron-catechol complexes [J].

Filippidi, Emmanouela ;

Cristiani, Thomas R. ;

Eisenbach, Claus D. ;

Waite, J. Herbert ;

Israelachvili, Jacob N. ;

Ahn, B. Kollbe ;

Valentine, Megan T. .

SCIENCE, 2017, 358 (6362) :502-505

← 1 2 3 4 5 6 7 →