Crystal structure of the binary complex of cobalt and zinc chlorides with carbamide [Co(OCN2H4)5(H2O)][ZnCl4]

被引：1

作者：

Furmanova, N. G. ^{[1
]}

Chernaya, T. S. ^{[1
]}

Resnyanskii, V. F. ^{[2
]}

Sulaimankulov, K. S. ^{[2
]}

机构：

[1] Russian Acad Sci, AV Shubnikov Crystallog Inst, Moscow 119333, Russia

[2] Natl Acad Sci Kyrgyzstan, Inst Chem & Chem Technol, Bishkek 720071, Kyrgyzstan

来源：

CRYSTALLOGRAPHY REPORTS | 2010年 / 55卷 / 02期

关键词：

Crystallography Report; Binary Complex; Cobalt Chloride; Cambridge Structural Database; Zinc Chloride;

D O I：

10.1134/S1063774510020124

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Mixed single crystals of [Co(OCN2H4)(5)(H2O)][ZnCl4] were grown by the isothermal evaporation of an aqueous solution. The crystal structure of this complex was established by X-ray diffraction (R = 0.052 based on 7003 reflections). The crystals consist of [Co(OCN2H4)(5)(H2O)](2+) cations containing Co atoms in an octahedral coordination and [ZnCl4](2-)] anions containing Zn atoms in a tetrahedral coordination. The carbamide molecules are involved in both intramolecular and interionic hydrogen bonds. The H2O molecule forms hydrogen bonds with the anions.

引用

页码：233 / 236

页数：4

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