Crystal structure of the binary complex of cobalt and zinc chlorides with carbamide [Co(OCN2H4)5(H2O)][ZnCl4]

被引：1
|
作者：
Furmanova, N. G. [1 ]
Chernaya, T. S. [1 ]
Resnyanskii, V. F. [2 ]
Sulaimankulov, K. S. [2 ]
机构：
[1] Russian Acad Sci, AV Shubnikov Crystallog Inst, Moscow 119333, Russia
[2] Natl Acad Sci Kyrgyzstan, Inst Chem & Chem Technol, Bishkek 720071, Kyrgyzstan
来源：
CRYSTALLOGRAPHY REPORTS | 2010年 / 55卷 / 02期
关键词：
Crystallography Report; Binary Complex; Cobalt Chloride; Cambridge Structural Database; Zinc Chloride;
D O I：
10.1134/S1063774510020124
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Mixed single crystals of [Co(OCN2H4)(5)(H2O)][ZnCl4] were grown by the isothermal evaporation of an aqueous solution. The crystal structure of this complex was established by X-ray diffraction (R = 0.052 based on 7003 reflections). The crystals consist of [Co(OCN2H4)(5)(H2O)](2+) cations containing Co atoms in an octahedral coordination and [ZnCl4](2-)] anions containing Zn atoms in a tetrahedral coordination. The carbamide molecules are involved in both intramolecular and interionic hydrogen bonds. The H2O molecule forms hydrogen bonds with the anions.
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页码：233 / 236
页数：4
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