Azo-hydrazo Tautomerism and Inclusion Complexation of 1-phenylazo-2-naphthols with Various Solvents and β-cyclodextrin

被引：16

作者：

Prabhu, A. Antony Muthu ^{[1
]}

Venkatesh, G. ^{[1
]}

Rajendiran, N. ^{[1
]}

机构：

[1] Annamalai Univ, Dept Chem, Annamalainagar 608002, Tamil Nadu, India

来源：

JOURNAL OF FLUORESCENCE | 2010年 / 20卷 / 04期

关键词：

1-phenyazo-2-naphthol; beta-cyclodextrin; Inclusion complex; Azo-hydrazo tautomerism; HOST-GUEST INTERACTIONS; INTRAMOLECULAR CHARGE-TRANSFER; ALPHA-CYCLODEXTRIN; DYNAMIC ASPECTS; MOLECULAR RECOGNITION; TRANS ISOMERIZATION; PROTON-TRANSFER; METHYL-ORANGE; SCHIFF-BASES; KINETICS;

D O I：

10.1007/s10895-010-0642-0

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Spectral characteristics of sudan I (SDI), sudan II (SDII) and mordant violet-5 (MV5) have been studied in various solvents and beta-cyclodextrin (beta-CD). The inclusion complex of the above molecules with beta-CD was analyzed by UV-visible, fluorometry, and DFT methods. The solvent study shows that azo-hydrazo tautomer is present in these molecules. The increase in the fluorescence intensity and a large bathochromic shift in the S-1 state indicate these molecules forms 1:1 inclusion complex with beta-CD.

引用

页码：961 / 972

页数：12

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