Extraction and electrochemical behavior of fission palladium in room-temperature ionic liquid

被引：14

作者：

Kumaresan, R. ^{[1
]}

Jain, Rakesh ^{[2
]}

Venkatesan, K. A. ^{[1
]}

Antony, M. P. ^{[1
]}

Bhanage, B. M. ^{[2
]}

机构：

[1] Indira Gandhi Ctr Atom Res, Div Fuel Chem, Kalpakkam 603102, Tamil Nadu, India

[2] Inst Chem Technol, Dept Chem, Bombay 400019, Maharashtra, India

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2015年 / 303卷 / 01期

关键词：

Fission palladium; Extraction; Ionic liquid; Tri-n-octylmethylammonium nitrate; Electrodeposition; RECOVERY; ACID; PLATINOIDS; LIGAND;

D O I：

10.1007/s10967-014-3734-5

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The extraction behavior of palladium in a solution of tri-n-octylmethylammonium nitrate (TOMAN) and 1,3-diisopropyl benzene (DIPB) in presence of tri-n-butyl phosphate as phase modifier was studied. The distribution ratio of palladium (D-Pd(II)) increased with increase in the concentration of nitric acid, reached a maximum at 1 M in nitric acid, followed by decrease in D-Pd(II) values. The cyclic voltammogram of the palladium in extracted organic phase (0.5 M TOMAN + 0.1 M TBP/DIPB) showed a surge in cathode current at -0.5 V was due to the palladium deposition. The results confirmed the feasibility of using the organic phase for electrodeposition of palladium directly from extracted phase.

引用

页码：1047 / 1052

页数：6

共 25 条

[21]

Sundram SK, 2000, PNNL13347

[22] The use of a rotating cylinder electrode to selective recover palladium from acid solutions used to manufacture automotive catalytic converters [J].

Terrazas-Rodriguez, J. E. ;

Gutierrez-Granados, S. ;

Alatorre-Ordaz, M. A. ;

de Leon, C. Ponce ;

Walsh, F. C. .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2011, 41 (01) :89-97

[23]

Venkatesan KA, 2010, CHEM RES APPL-NOVA, P405

[24] Extraction of palladium from nitric acid medium by commercial resins with phosphinic acid, methylene thiol and isothiouronium moieties attached to polystyrene-divinylbenzene [J].

Venkatesan, KA ;

Selvan, BR ;

Antony, MP ;

Srinivasan, TG ;

Rao, PRV .

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2005, 266 (03) :431-440

[25] Adsorption properties and behavior of the platinum group metals onto a silica-based (Crea + TOA)/SiO2-P adsorbent from simulated high level liquid waste of PUREX reprocessing [J].

Xu, Yuanlai ;

Kim, Seong-Yun ;

Ito, Tatsuya ;

Tada, Tsutomu ;

Hitomi, Keitaro ;

Ishii, Keizo .

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2013, 297 (01) :41-48

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