Extraction and electrochemical behavior of fission palladium in room-temperature ionic liquid

被引：14

作者：

Kumaresan, R. ^{[1
]}

Jain, Rakesh ^{[2
]}

Venkatesan, K. A. ^{[1
]}

Antony, M. P. ^{[1
]}

Bhanage, B. M. ^{[2
]}

机构：

[1] Indira Gandhi Ctr Atom Res, Div Fuel Chem, Kalpakkam 603102, Tamil Nadu, India

[2] Inst Chem Technol, Dept Chem, Bombay 400019, Maharashtra, India

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2015年 / 303卷 / 01期

关键词：

Fission palladium; Extraction; Ionic liquid; Tri-n-octylmethylammonium nitrate; Electrodeposition; RECOVERY; ACID; PLATINOIDS; LIGAND;

D O I：

10.1007/s10967-014-3734-5

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The extraction behavior of palladium in a solution of tri-n-octylmethylammonium nitrate (TOMAN) and 1,3-diisopropyl benzene (DIPB) in presence of tri-n-butyl phosphate as phase modifier was studied. The distribution ratio of palladium (D-Pd(II)) increased with increase in the concentration of nitric acid, reached a maximum at 1 M in nitric acid, followed by decrease in D-Pd(II) values. The cyclic voltammogram of the palladium in extracted organic phase (0.5 M TOMAN + 0.1 M TBP/DIPB) showed a surge in cathode current at -0.5 V was due to the palladium deposition. The results confirmed the feasibility of using the organic phase for electrodeposition of palladium directly from extracted phase.

引用

页码：1047 / 1052

页数：6

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