Hydrothermal synthesis and structural characterization of a novel open-framework cobalt phosphate, CO2(HPO4)2 • H2O, with 1-D helical channels

被引：0
作者：
Zeng, QX
Chen, LS
Li, YF
Yang, GY [1 ]
Xu, JQ
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Stuct Chem, Fuzhou 350002, Peoples R China
[2] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China
[3] Jinzhiu Med Coll, Fac Basic Sci, Jinzhou 121000, Peoples R China
来源：
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2003年 / 24卷 / 01期
关键词：
hydrothermal synthesis; cobalt phosphate; crystal structure;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new Co-2 (HPO4)(2) . H2O has been hydrothermally synthesized firstly, Single crystal X-ray analysis indicates that this compound crystallizes in a hexagonal, system, space. group P6(5) with a=1.048 31(05) nm, b=1.048 31(15) nm, c=1.496 3(3) nm, alpha=90degrees, beta=90degrees, gamma=120degrees, V=1.424 1(4) nm(3), mu=3.849 mm(-1). Z=6, F(000)=960, D-c=2.294 g/cm(3), R=0.072 1, wR=0.212 1, S=1.182, Deltarho(max)=1.671X10(3) e (.) nm(-3) and (Deltarho)(min)=-1.210X10(3) e (.) nm(-3). Co-2(HPO4)(2) . H2O Is characterized by ID 12-ring helical channels. Tetrahedral primary structure-building units of CoO4 and PO4 indicates the title compound. has a zeotype framework.
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页码：31 / 33
页数：3
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