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A water-stable 3D Zn(II) luminescent coordination polymer for highly sensitive and selective sensing of acetylacetone and Fe3+ ion
被引:6
|作者:
Cui, Jia-Ning
[1
]
Zhu, Hui
[2
]
Cui, Guang-Hua
[2
]
机构:
[1] Caofeidian Coll Technol, Dept Engn, 25 Xingzhi Rd, Tangshan 063200, Hebei, Peoples R China
[2] North China Univ Sci & Technol, Coll Chem Engn, 21 Bohai Rd, Tangshan 063210, Hebei, Peoples R China
关键词:
Acetylacetone;
Coordination polymer;
Fe3+ ions;
Luminescent sensing;
Zinc(II);
METAL-ORGANIC FRAMEWORK;
SENSORS;
ANIONS;
ANTIBIOTICS;
LIGANDS;
SITES;
PROBE;
D O I:
10.1016/j.inoche.2021.108654
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
A water-stable luminescent coordination polymer [Zn(L)(0.5)(2,6-NDC)](n) (1) (L = 1,6-bis(1-(pyridin-4-ylmethyl)-1H-benzo[d]imidazol-2-yl)hexane, 2,6-H2NDC = 2,6-naphthalenedicarboxylic acid) was hydmthermally synthesized and characterized. 1 possesses a 3D framework with 6-connected pcu topology. The structure of 1 could remain stable during the pH of 3.0-11.0. 1 can be utilized as a quick-responsive luminescent probe for sensing of acetylacetone (acac) and Fe3+ ions. The limit of detection is 5.29 mu M for acac, and 0.82 mu M for Fe3+, respectively.
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页数:5
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