A water-stable 3D Zn(II) luminescent coordination polymer for highly sensitive and selective sensing of acetylacetone and Fe3+ ion

被引：6

作者：

Cui, Jia-Ning ^{[1
]}

Zhu, Hui ^{[2
]}

Cui, Guang-Hua ^{[2
]}

机构：

[1] Caofeidian Coll Technol, Dept Engn, 25 Xingzhi Rd, Tangshan 063200, Hebei, Peoples R China

[2] North China Univ Sci & Technol, Coll Chem Engn, 21 Bohai Rd, Tangshan 063210, Hebei, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2021年 / 129卷

关键词：

Acetylacetone; Coordination polymer; Fe3+ ions; Luminescent sensing; Zinc(II); METAL-ORGANIC FRAMEWORK; SENSORS; ANIONS; ANTIBIOTICS; LIGANDS; SITES; PROBE;

D O I：

10.1016/j.inoche.2021.108654

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A water-stable luminescent coordination polymer [Zn(L)(0.5)(2,6-NDC)](n) (1) (L = 1,6-bis(1-(pyridin-4-ylmethyl)-1H-benzo[d]imidazol-2-yl)hexane, 2,6-H2NDC = 2,6-naphthalenedicarboxylic acid) was hydmthermally synthesized and characterized. 1 possesses a 3D framework with 6-connected pcu topology. The structure of 1 could remain stable during the pH of 3.0-11.0. 1 can be utilized as a quick-responsive luminescent probe for sensing of acetylacetone (acac) and Fe3+ ions. The limit of detection is 5.29 mu M for acac, and 0.82 mu M for Fe3+, respectively.

引用

页数：5

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