Sonochemical synthesis of CdSe hollow spherical assemblies via an in-situ template route

被引:214
作者
Zhu, JJ [1 ]
Xu, S
Wang, H
Zhu, JM
Chen, HY
机构
[1] Nanjing Univ, Dept Chem, Lab Mesoscop Mat Sci, Nanjing 210093, Peoples R China
[2] Nanjing Univ, Dept Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[3] Nanjing Univ, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China
关键词
D O I
10.1002/adma.200390033
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
CdSe hollow spherical assemblies composed of 5 nm nanoparticles have been synthesized sonochemically. During the process, amorphous Cd(OH)(2), which acts as the in-situ template, directs the growth of primary CdSe nanoparticles on its surface and their assembly into hollow spherical structures. The Figure is a schematic of the proposed mechanism for the formation of the hollow chalcogenide spheres.
引用
收藏
页码:156 / +
页数:5
相关论文
共 31 条
[11]   Nanocages derived from shell cross-linked micelle templates [J].
Huang, HY ;
Remsen, EE ;
Kowalewski, T ;
Wooley, KL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (15) :3805-3806
[12]   Nanostructured molybdenum carbide: Sonochemical synthesis and catalytic properties [J].
Hyeon, TH ;
Fang, MM ;
Suslick, KS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (23) :5492-5493
[13]   Sonochemical and microwave-assisted preparations of PbTe and PbSe. A comparative study [J].
Kerner, R ;
Palchik, O ;
Gedanken, A .
CHEMISTRY OF MATERIALS, 2001, 13 (04) :1413-1419
[14]  
Klug H., 1962, X-Ray Diffraction Procedures
[15]   Sonochemical synthesis and characterization of nanometer-size transition metal oxides from metal acetates [J].
Kumar, RV ;
Diamant, Y ;
Gedanken, A .
CHEMISTRY OF MATERIALS, 2000, 12 (08) :2301-2305
[16]   Hierarchical order in hollow spheres of mesoporous silicates [J].
Lin, HP ;
Cheng, YR ;
Mou, CY .
CHEMISTRY OF MATERIALS, 1998, 10 (12) :3772-+
[17]   Production of hollow polymeric microspheres by surface-confined living radical polymerization on silica templates [J].
Mandal, TK ;
Fleming, MS ;
Walt, DR .
CHEMISTRY OF MATERIALS, 2000, 12 (11) :3481-3487
[18]   A process for preparation of Q-CdSe thin films by liquid-liquid interface reaction technique [J].
Patil, KR ;
Paranjape, DV ;
Sathaye, SD ;
Mitra, A ;
Padalkar, SR ;
Mandale, AB .
MATERIALS LETTERS, 2000, 46 (2-3) :81-85
[19]  
Suslick K. S., 1988, ULTRASOUND ITS CHEM
[20]   THE SONOCHEMICAL HOT-SPOT [J].
SUSLICK, KS ;
HAMMERTON, DA ;
CLINE, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (18) :5641-5642