Syntheses, Crystal Structures and Photoluminescent Properties of Pb(II) Complexes Constructed from 1,10-Phenanthroline Derivatives and 1,12-Dodecanedioic Acid

被引:0
|
作者
Li Xiu-Ying [1 ,2 ]
Gao Lin [3 ]
Che Guang-Bo [2 ]
Yan Yong-Sheng [3 ]
Guan Qing-Feng [1 ]
机构
[1] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Jiangsu, Peoples R China
[2] Jilin Normal Univ, Chinese Minist Educ, Key Lab Preparat & Applicat Environm Friendly Mat, Siping 136000, Jilin, Peoples R China
[3] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China
关键词
lead(II) complex; 1,10-phenanthroline derivatives; 1,12-dodecanedioic acid; crystal structure; photoluminescent property; METAL-ORGANIC FRAMEWORKS; HYDROTHERMAL SYNTHESIS; COORDINATION POLYMERS; HYBRID MATERIALS; HYDROGEN; SERIES; LIGANDS; STORAGE; MN(II); CU(II);
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two Pb(II) metal-organic complexes, namely [Pb(TCPP)(DDA)(0.5)(NO3)](n) (1) and [Pb(TCPB)(DDA)(0.5)](n) (2) (TCPP=2-(1H-1,3,7,8-Tetraaza-cyclopenta [l]phenanthren-2-yl)phenol, TCPB=2-(1H-1,3,7,8-Tetraaza-cyclopenta[l]phenanthren-2-yl)benzoic acid, H(2)DDA =1,12-dodecanedioic acid), based on the mixed ligands of 1,10-phenanthroline derivatives and H(2)DDA were synthesized and characterized by elemental analyses, IR spectra, and single-crystal X-ray diffraction. The complex 1 presents the (6,3)-connected 2D nets, which are connected through pi-pi interactions to generate 3D supermolecular structure. While complex 2 is a 2D layer structure with (4,4)-connected topology constructed by TCPB and DDA ligands linking Pb(II) atoms. Furthermore, complexes 1 and 2 exhibit green photoluminescent properties at room temperature. CCDC: 989785, 1; 989786, 2.
引用
收藏
页码:2669 / 2674
页数:6
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