Synthesis and optical properties of novel red phosphors Sr3MoO6:Eu3+ with highly enhanced emission by W6+ doping

被引：29

作者：

Jing, Lindan ^{[1
]}

Liu, Xiaohua ^{[1
]}

Li, Yuntong ^{[1
]}

机构：

[1] Guangdong Univ Technol, Sch Phys & Optoelect Engn, Guangzhou 510006, Guangdong, Peoples R China

来源：

JOURNAL OF LUMINESCENCE | 2015年 / 158卷

关键词：

Phosphor; Photoluminescence; Sr3MoO6:Eu3+; PHOTOLUMINESCENCE PROPERTIES; COPRECIPITATION SYNTHESIS; EMITTING PHOSPHOR; LUMINESCENCE; EU3+; LN(3+);

D O I：

10.1016/j.jlumin.2014.10.038

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Sr3-xEuxMoO6 and Sr2.7Eu0.3Mo1-yWyO6 red phosphors were successfully synthesized by solid-state reaction method at 1260 degrees C for 6 h. The photoluminescence (PL) properties of Eu3+ in this phosphor material were investigated by analyzing the excitation and emission spectra and the effect of Eu3+ concentration. X-ray diffraction (XRD) patterns indicate the formation of Sr3MoO6:Eu3+ pure phase. The excitation and emission spectra demonstrate that 30 mol% Eu3+ :Sr3MoO6 shows a broad charge-transfer (CT) band at around 365 nm and an intense red emission (616 nm, D-5(0)-> F-7(2) transition), with Commission Internationale de l'Eclairage (CIE) chromaticity coordinates (0.619, 0.376). The substitution of Mo6+ with W6+ results in a considerable enhancement of luminescence intensity and improved red color purity. All the results imply that the studied phosphors may be a promising red component for the application in the white light emitting diodes. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：351 / 355

页数：5

共 27 条

[1] Sol-gel synthesis and optical improvement of novel red-emitting [LiY(1-x)Eux][MoyW(1-y)O4]2 powder for white LED applications [J].

Cao, Fa-bin .

JOURNAL OF LUMINESCENCE, 2012, 132 (03) :641-644

[2] Structure and photoluminescence properties of La2Mo(W)O6:Eu3+ as red phosphors for white LED applications [J].

Chen, Fengming ;

Liu, Xiaohua .

OPTICAL MATERIALS, 2013, 35 (12) :2716-2720

[3] A simple route to synthesize multiform structures of tin oxide nanobelts and optical properties investigation [J].

Cheng, Chuanwei ;

Xu, Guoyue ;

Zhang, Haiqian ;

Li, Yingying ;

Luo, Yan ;

Zhang, Peigen .

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2008, 147 (01) :79-83

[4] Synthesis and photoluminescence characteristics of Ln3+ (Ln = Sm, Er and Dy)-doped BaGd2(MoO4)4 phosphors [J].

Deng, Yaomin ;

Yi, Shuangping ;

Wang, Yinhai ;

Xian, Jieqiang .

OPTICAL MATERIALS, 2014, 36 (08) :1378-1383

[5] THEORY OF CONCENTRATION QUENCHING IN INORGANIC PHOSPHORS [J].

DEXTER, DL ;

SCHULMAN, JH .

JOURNAL OF CHEMICAL PHYSICS, 1954, 22 (06) :1063-1070

[6] Photoluminescence characterization of Ca10Na(PO4)7:Eu3+ red-emitting phosphor [J].

Dou, Xihua ;

Zhao, Weiren ;

Song, Enhai ;

Zhou, Guoxiong ;

Yi, Chunyu ;

Zhou, Mingkang .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2011, 78 (02) :821-825

[7] Co-precipitation synthesis and photoluminescence properties of Ba1-xMoO4:xEu3+ red phosphors [J].

Feng, Wen-Lin ;

Jin, Ye ;

Wu, Ying ;

Li, Deng-Feng ;

Cai, An-Kang .

JOURNAL OF LUMINESCENCE, 2013, 134 :614-617

[8]

Givargizov E.I., 1987, HIGHLY ANISOTROPIC C

[9] Methods to improve the fluorescence intensity of CaS:Eu2+ red-emitting phosphor for white LED [J].

Guo, Chongfeng ;

Huang, Dexiu ;

Su, Qiang .

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2006, 130 (1-3) :189-193

[10] A novel red phosphor for white light emitting diodes [J].

Hu, YS ;

Zhuang, WD ;

Ye, HQ ;

Wang, DH ;

Zhang, SS ;

Huang, XW .

JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 390 (1-2) :226-229

← 1 2 3 →