Gold-catalyzed C-S bond formation from thiols

被引：67
|
作者：
Jean, Mickael [1 ]
Renault, Jacques [1 ]
van de Weghe, Pierre [1 ]
Asao, Naoki [2 ,3 ]
机构：
[1] Univ Rennes 1, EA Subst Lichen & Photoprotect, Fac Sci Biol & Pharmaceut, F-35043 Rennes, France
[2] Tohoku Univ, Dept Chem, Sendai, Miyagi 9808578, Japan
[3] Tohoku Univ, Res & Analyt Ctr Giant Mol, Grad Sch Sci, Sendai, Miyagi 9808578, Japan
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 02期
关键词：
Gold catalysis; Substitution; Sulfide; CARBON-SULFUR; ARYL HALIDES; PALLADIUM; SULFIDES; ALKYNES; CYCLOISOMERIZATION; CARBOALKOXYLATION; CONDENSATION; PLATINUM; BROMIDE;
D O I：
10.1016/j.tetlet.2009.11.025
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
ortho-Alkynylbenzoic acid alkyl esters act as alkylating agents of thiol derivatives with PPh3AuCl in combination with AgOTf in 1,2-dichloroethane at 80 degrees C. The corresponding sulfide compounds are obtained in good to excellent yields. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：378 / 381
页数：4
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