Abuse behavior of high-power, lithium-ion cells

被引:945
作者
Spotnitz, R
Franklin, J
机构
[1] Battery Design Co, Pleasanton, CA 94588 USA
[2] Solvay Res & Technol, B-1120 Brussels, Belgium
关键词
simulation; thermal; lithium-ion battery; polyvinylidene fluoride; binder;
D O I
10.1016/S0378-7753(02)00488-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Published accounts of abuse testing of lithium-ion cells and components are summarized, including modeling work. From this summary, a set of exothermic reactions is selected with corresponding estimates of heats of reaction. Using this set of reactions, along with estimated kinetic parameters and designs for high-rate batteries, models for the abuse behavior (oven, short-circuit, overcharge, nail, crush) are developed. Finally, the models are used to determine that fluorinated binder plays a relatively unimportant role in thermal runaway. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:81 / 100
页数:20
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