Rapid production of silicon-containing vapor grown carbon fibers using the liquid pulse injection technique

被引:3
|
作者
Mukai, SR [1 ]
Masuda, T [1 ]
Harada, T [1 ]
Hashimoto, K [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Div Chem Engn, Kyoto 6068501, Japan
关键词
carbon fibers; catalytically grown carbon; chemical vapor deposition; electrochemical analysis; reactivity;
D O I
10.1016/S0008-6223(00)00023-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Silicon containing vapor grown carbon fibers have been rapidly produced from a mixture of benzene and phenyl silane, using the liquid pulse injection technique. Fibers with lengths up to 20 mm were obtained within 1 min at a carbon yield of 0.23. The inclusion of silicon led to the improvement in the oxidation resistivity of the fibers. Moreover, the obtained fibers possessed tensile strengths and electrical resistivities comparable to those of fibers without silicon inclusion. Electrochemical analysis suggests that the included silicon is highly dispersed within the structure of the fibers. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1801 / 1805
页数:5
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