Synthesis of aziridines from imines and ethyl diazoacetate in room temperature ionic liquids

被引:87
|
作者
Sun, W [1 ]
Xia, CG [1 ]
Wang, HW [1 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/S0040-4039(03)00185-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis of aziridines from imines and ethyl diazoacetate in room temperature ionic liquids is reported. The reactions proceed readily under mild conditions with high cis selectivities and high yields. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2409 / 2411
页数:3
相关论文
共 50 条
  • [1] CATALYTIC FORMATION OF AZIRIDINES FROM IMINES AND DIAZOACETATE
    RASMUSSEN, KG
    JORGENSEN, KA
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (14) : 1401 - 1402
  • [2] Metal-catalysed reactions of imines with ethyl diazoacetate leading to aziridines
    Rasmussen, KG
    Jorgensen, KA
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (09): : 1287 - 1291
  • [3] Monomeric rhodium(II) catalysts for the preparation of aziridines and enantioselective formation of cyclopropanes from ethyl diazoacetate at room temperature
    Krumper, JR
    Gerisch, M
    Suh, JM
    Bergman, RG
    Tilley, TD
    JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (25) : 9705 - 9710
  • [4] Synthesis of room temperature ionic liquids
    Alquzah, Omar
    Hayden, Tiffany
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [5] Synthesis of room temperature ionic liquids from carboxymethylated chitosan
    Huang, Ling
    Zhai, Maolin
    Peng, Jing
    Xu, Ling
    Li, Jiuqiang
    Wei, Genshuan
    CARBOHYDRATE POLYMERS, 2008, 71 (04) : 690 - 693
  • [6] Synthesis of flavonoids in room temperature ionic liquids
    Johnson, Clay
    Manchanayakage, Renuka
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [7] Peptide synthesis in room temperature ionic liquids
    Vallette, H
    Ferron, L
    Coquerel, G
    Gaumont, AC
    Plaquevent, JC
    TETRAHEDRON LETTERS, 2004, 45 (08) : 1617 - 1619
  • [8] Progress in synthesis of aziridines from imines
    Huang, D
    Yan, M
    Shen, Q
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2004, 24 (10) : 1200 - 1212
  • [9] Room Temperature Ionic Liquids as Homogeneous Supports for Synthesis
    Handy, Scott T.
    Okello, Maurice
    Bwambok, David
    IONIC LIQUIDS IN ORGANIC SYNTHESIS, 2007, 950 : 116 - 126
  • [10] Improved synthesis of room temperature ionic liquids.
    Namboodiri, VV
    Varma, RS
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : U650 - U650