Electrochemical polymerization and characterization of polypyrrole nanowires and nanotubules

被引:19
作者
Chen, Y. F. [1 ,2 ]
Liu, J.
Yao, H. J.
Mo, D.
Duan, J. L.
Hou, M. D.
Sun, Y. M.
Zhang, L.
Maaz, K. [3 ]
机构
[1] Chinese Acad Sci, Inst Modern Phys, Mat Grp 2, Lanzhou 730000, Gansu, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
[3] PINSTECH, Div Phys, Islamabad, Pakistan
基金
中国国家自然科学基金;
关键词
Polypyrrole nanostructure; Etched ion-track template; Optical absorption; CHEMICAL-SYNTHESIS; DOPED POLYPYRROLE; FIELD-EMISSION; NANOSTRUCTURES; FABRICATION; MORPHOLOGY; NANOMATERIALS; POLYANILINE; GENERATION; BIPOLARONS;
D O I
10.1016/j.physb.2010.03.009
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Polypyrrole nanostructure arrays, including simultaneously large quantities of nanowires and small quantities of partially filled nanotubules have been electrochemically synthesized in home-made etched ion-track polycarbonate (PC) templates. Diameter of the prepared nanostructures varies from 45 to 320 nm with their lengths up to 30 microns. Morphological studies of these nanostructures were performed by field emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM) and Raman spectroscopy. While optical absorption properties were studied by ultraviolet-visible-near infrared spectrophotometry (UV-vis-NIR). It has been observed that the absorption maximum of polypyrrole shifts to the longer wavelength side as the diameter of these nanostructures (nanowires and nanotubules) increases. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:2461 / 2465
页数:5
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