CeO2 nanoparticles@ NiFe-LDH nanosheet heterostructure as electrocatalysts for oxygen evolution reaction

被引:32
|
作者
Dong, Qibing [1 ,2 ,3 ]
Shuai, Chao [1 ,2 ,3 ]
Mo, Zunli [1 ,2 ,3 ]
Liu, Nijuan [1 ,2 ,3 ]
Liu, Guigui [1 ,2 ,3 ]
Wang, Jia [1 ,2 ,3 ]
Pei, Hebing [1 ,2 ,3 ]
Jia, Qianqian [1 ,2 ,3 ]
Liu, Wentong [1 ,2 ,3 ]
Guo, Xudong [1 ,2 ,3 ]
机构
[1] Res Ctr Gansu Mil & Civilian Integrat Adv Struct, Lanzhou 730070, Peoples R China
[2] Minist Educ China Lanzhou, Key Lab Ecoenvironm Related Polymer Mat, Lanzhou 730070, Peoples R China
[3] Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Polymer Mat Gansu Prov, Lanzhou 730070, Peoples R China
关键词
CeO2; NiFe-LDH; Heterostructure; Excellent OER activity; LAYERED DOUBLE-HYDROXIDE; BIFUNCTIONAL ELECTROCATALYST; EFFICIENT ELECTROCATALYSTS; DOPED CARBON; REACTION OER; PERFORMANCE; CATALYSTS; GRAPHENE; ARRAYS; NIO;
D O I
10.1016/j.jssc.2021.121967
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The development of high-efficiency and low-cost electrocatalysts for electrolyzed splitting water to release oxygen has attracted widespread attention. In this work, the n-n heterostructure CeO2 /NiFe-LDH electrocatalysts were synthesized through a simple hydrothermal reaction process. The heterostructure and morphology of feature were characterized by X-ray diffraction, X-ray photoelectron spectroscopy scanning electron microscope and transmission electron microscope and studied for OER catalyst activity. The fabricated CeO2 /NiFe-LDH exhibited excellent OER activity with a low overpotential of 246 mV at the current density of 10 mA cm(-2), a small Tafel slope of 65 mV dec(-1), and good stability, due to the positively charged n-type semiconductor promoting the adsorption of OH , and the synergy effect of CeO2 and NiFe-LDH for the OER activity. This work provided a general strategy for designing simple synthesis of heterostructure OER electrocatalysts.
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页数:7
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