Nonlinear relationship between the Product Consistency Test (PCT) response and the Al/B ratio in a soda-lime aluminoborosilicate glass

被引：5

作者：

Farooqi, Rahmat Ullah ^{[1
]}

Hrma, Pavel ^{[1
,2
]}

机构：

[1] Pohang Univ Sci & Technol, Div Adv Nucl Engn, 77 Cheongam Ro, Pohang 790784, Gyeongbuk, South Korea

[2] Pacific NW Natl Lab, Richland, WA 99352 USA

来源：

JOURNAL OF NUCLEAR MATERIALS | 2016年 / 474卷

基金：

新加坡国家研究基金会;

关键词：

Aluminoborosilicate glasses; Product consistency test; Durable glasses; Charge compensation effect; BOROSILICATE GLASSES; DISSOLUTION; CORROSION; TERM;

D O I：

10.1016/j.jnucmat.2016.02.017

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We have investigated the effect of Al/B ratio on the Product Consistency Test (PCT) response. In an aluminoborosilicate soda-lime glass based on a modified International Simple Glass, ISG-3, the Al/B ratio varied from 0 to 0.55 (in mole fractions). In agreement with various models of the PCT response as a function of glass composition, we observed a monotonic increase of B and Na releases with decreasing Al/B mole ratio, but only when the ratio was higher than 0.05. Below this value (Al/B < 0.05), we observed a sharp decrease that we attribute to B in tetrahedral coordination. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：28 / 34

页数：7

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