Metal-assisted chemical etching for very high aspect ratio grooves in n-type silicon wafers

被引:11
作者
Booker, Katherine [1 ]
Brauers, Maureen [1 ]
Crisp, Erin [1 ]
Rahman, Shakir [1 ]
Weber, Klaus [1 ]
Stocks, Matthew [1 ]
Blakers, Andrew [1 ]
机构
[1] Australian Natl Univ, Coll Engn & Comp Sci, Ctr Sustainable Energy Syst, Canberra, ACT 0200, Australia
关键词
metal assisted etching; surface roughness; high aspect ratio; vertical grooves; CATALYSTS; NANOWIRES; ARRAYS; FILMS;
D O I
10.1088/0960-1317/24/12/125026
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Metal-assisted chemical etching (MACE) is an inexpensive, simple method for etching silicon structures, including the etching of high aspect ratio grooves. We improve on the best reported results in this area by etching grooves with aspect ratios of 65 (vertical depths 650 mu m) in n-type silicon. The grooves maintain an excellent degree of verticality and show minimal width variation. We elucidate some limiting factors and demonstrate the effect of silicon surface roughness on the groove etching.
引用
收藏
页数:6
相关论文
共 18 条
[1]   Porosity control in metal-assisted chemical etching of degenerately doped silicon nanowires [J].
Balasundaram, Karthik ;
Sadhu, Jyothi S. ;
Shin, Jae Cheol ;
Azeredo, Bruno ;
Chanda, Debashis ;
Malik, Mohammad ;
Hsu, Keng ;
Rogers, John A. ;
Ferreira, Placid ;
Sinha, Sanjiv ;
Li, Xiuling .
NANOTECHNOLOGY, 2012, 23 (30)
[2]   Optical Characterization of High-Order 1-D Silicon Photonic Crystals [J].
Barillaro, Giuseppe ;
Strambini, Lucanos Marsilio ;
Annovazzi-Lodi, Valerio ;
Merlo, Sabina .
IEEE JOURNAL OF SELECTED TOPICS IN QUANTUM ELECTRONICS, 2009, 15 (05) :1359-1367
[3]   Thermal conductivities of evaporated gold films on silicon and glass [J].
Chen, G ;
Hui, P .
APPLIED PHYSICS LETTERS, 1999, 74 (20) :2942-2944
[4]   Nonlithographic Patterning and Metal-Assisted Chemical Etching for Manufacturing of Tunable Light-Emitting Silicon Nanowire Arrays [J].
Chern, Winston ;
Hsu, Keng ;
Chun, Ik Su ;
de Azeredo, Bruno P. ;
Ahmed, Numair ;
Kim, Kyou-Hyun ;
Zuo, Jian-min ;
Fang, Nick ;
Ferreira, Placid ;
Li, Xiuling .
NANO LETTERS, 2010, 10 (05) :1582-1588
[5]   Role of catalyst concentration on metal assisted chemical etching of silicon [J].
Cichoszewski, J. ;
Reuter, M. ;
Schwerdt, F. ;
Werner, J. H. .
ELECTROCHIMICA ACTA, 2013, 109 :333-339
[6]   Preparation of thin porous silicon layers by stain etching [J].
DimovaMalinovska, D ;
SendovaVassileva, M ;
Tzenov, N ;
Kamenova, M .
THIN SOLID FILMS, 1997, 297 (1-2) :9-12
[7]   Model for the Mass Transport during Metal-Assisted Chemical Etching with Contiguous Metal Films As Catalysts [J].
Geyer, Nadine ;
Fuhrmann, Bodo ;
Huang, Zhipeng ;
de Boor, Johannes ;
Leipner, Hartmut S. ;
Werner, Peter .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (24) :13446-13451
[8]   Fabrication of Silicon Nanowires with Precise Diameter Control Using Metal Nanodot Arrays as a Hard Mask Blocking Material in Chemical Etching [J].
Huang, Jinquan ;
Chiam, Sing Yang ;
Tan, Hui Huang ;
Wang, Shijie ;
Chim, Wai Kin .
CHEMISTRY OF MATERIALS, 2010, 22 (13) :4111-4116
[9]   Oxidation Rate Effect on the Direction of Metal-Assisted Chemical and Electrochemical Etching of Silicon [J].
Huang, Zhipeng ;
Shimizu, Tomohiro ;
Senz, Stephan ;
Zhang, Zhang ;
Geyer, Nadine ;
Goesele, Ulrich .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (24) :10683-10690
[10]   Ordered Arrays of Vertically Aligned [110] Silicon Nanowires by Suppressing the Crystallographically Preferred Etching Directions [J].
Huang, Zhipeng ;
Shimizu, Tomohiro ;
Senz, Stephan ;
Zhang, Zhang ;
Zhang, Xuanxiong ;
Lee, Woo ;
Geyer, Nadine ;
Goesele, Ulrich .
NANO LETTERS, 2009, 9 (07) :2519-2525