The Changes of Thermal, Dielectric, and Optical Properties at Insertion of Small Concentrations of Ammonium to K3H(SO4)2 Crystals

被引：5
|
作者：
Selezneva, E. V. [1 ]
Makarova, I. P. [1 ]
Grebenev, V. V. [1 ]
Malyshkina, I. A. [2 ]
Komornikov, V. A. [1 ]
Gavrilova, N. D. [2 ]
Chitra, R. [3 ]
Choudhury, R. R. [3 ]
机构：
[1] Russian Acad Sci, Fed Sci Res Ctr Crystallog & Photon, Shubnikov Inst Crystallog, Moscow 119333, Russia
[2] Moscow MV Lomonosov State Univ, Fac Phys, Moscow 119991, Russia
[3] Bhabha Atom Res Ctr, Div Solid State Phys, Bombay 400085, Maharashtra, India
来源：
CRYSTALLOGRAPHY REPORTS | 2018年 / 63卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
PHASE-TRANSITIONS; SUBSTITUTION; SYSTEM;
D O I：
10.1134/S1063774518040247
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The structure of (K1-x (NH4) (x) )(3)H(SO4)(2) crystals with a low ammonium concentration and the behavior of their thermal, optical, and dielectric properties in a temperature range of 275-500 K have been investigated to clarify the influence of doping on the phase transition kinetics. An examination of unit-cell parameters of (K1 - x (NH4) (x) )(3)H(SO4)(2) single crystals has confirmed the existence of a superprotonic phase transition at a temperature of ae450K. The conducting properties of single-crystal and polycrystalline samples have been studied.
引用
收藏
页码：553 / 562
页数：10
相关论文
共 48 条
  • [1] Preparation and studies of new crystals in the K3H(SO4)2-(NH4)3H(SO4)2-H2O system
    Dmitricheva, E. V.
    Makarova, I. P.
    Grebenev, V. V.
    Dolbinina, V. V.
    Verin, I. A.
    CRYSTALLOGRAPHY REPORTS, 2014, 59 (03) : 344 - 352
  • [2] Dielectric Properties and Conductivity of (K,NH4)3H(SO4)2 Single Crystals at Low Potassium Concentrations
    Malyshkina, I. A.
    Selezneva, E. V.
    Makarova, I. P.
    Gavrilova, N. D.
    MOSCOW UNIVERSITY PHYSICS BULLETIN, 2019, 74 (04) : 392 - 399
  • [3] Studies of ferroelastic domain structures in (NH4)(3)H(SO4)(2), K3H(SO4)(2) and Rb3H(SeO4)(2) crystals
    Chen, RH
    Chen, TM
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1997, 58 (01) : 161 - &
  • [4] Mechanism of quantum effects in hydrogen-bonded crystals of the K3H(SO4)2 group
    Merunka, Dalibor
    Rakvin, Boris
    PHYSICAL REVIEW B, 2009, 79 (13)
  • [5] Ferroelastic property and nuclear magnetic resonance in a K3H(SO4)2 single crystal
    Lim, AR
    Jang, TG
    Chang, JH
    Jeong, SY
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2004, 73 (10) : 2863 - 2867
  • [6] Electron paramagnetic resonance investigation of K3H(SO4)2 proton conductor doped with Cr5+ ion
    Waplak, S
    Bednarski, W
    Ostrowski, A
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2003, 64 (02) : 229 - 235
  • [7] Effect of temperature and high pressure on Mn2+ EPR spectra in K3H(SO4)2 fast-proton conductor
    Ostrowski, Adam
    Krupska, Aldona
    PHASE TRANSITIONS, 2006, 79 (6-7) : 569 - 575
  • [8] The structure of (K0.43(NH4)0.57)3H(SO4)2 single crystals
    Dmitricheva, E. V.
    Makarova, I. P.
    Grebenev, V. V.
    CRYSTALLOGRAPHY REPORTS, 2015, 60 (06) : 814 - 820
  • [9] Investigation of the structure and properties of K9H7(SO4)8 • H2O single crystals
    Makarova, I. P.
    Chernaya, T. S.
    Grebenev, V. V.
    Dolbinina, V. V.
    Verin, I. A.
    Simonov, A. A.
    CRYSTALLOGRAPHY REPORTS, 2011, 56 (06) : 994 - 1003
  • [10] Implementation of Phase Transitions in Rb3H(SO4)2 under K Substitution
    Timakov, Ivan S.
    Komornikov, Vladimir A.
    Selezneva, Elena V.
    Grebenev, Vadim V.
    CRYSTALS, 2023, 13 (09)
12345