Reciprocal system 3Tl2S+Bi2Se3⇆3Tl2Se+Bi2S3

被引：3
|
作者：
Dzhafarov, Ya. I. [1 ]
Mirzoeva, A. M. [1 ]
Babanly, M. B. [1 ]
机构：
[1] Rasul Zade State Univ, Baku 370148, Azerbaijan
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 51卷 / 05期
关键词：
Phase Diagram; Solid Solution; Diffraction Analysis; Powder Diffraction; Liquidus Surface;
D O I：
10.1134/S0036023606050202
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reciprocal system 3Tl(2)S + Bi2Se3 <-> 3Tl(2)Se + Bi2S3 has been investigated by DTA, X-ray powder diffraction analysis, and emf measurements. Some polythermal sections and the isothermal section at 500 K of the phase diagram and the projection of the liquidus surface of this system have been constructed, and the types and coordinates of the invariant and univariant equilibria have been determined. The existence of wide regions of quaternary solid solutions based on the binary compounds Tl2S, Tl2Se, Bi2S3, and Bi2Se3, and solid solutions between the temary compounds TlBiS2 and TlBiSe2 have been established.
引用
收藏
页码：805 / 809
页数：5
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