Comparative Studies on Spectroscopic and Crystallization Properties of Al2O3-Li2O- B2O3-TiO2 Glasses

被引:58
作者
Alomairy, Sultan [1 ]
Aboraia, A. M. [2 ,3 ]
Shaaban, E. R. [3 ]
Shaaban, Kh. S. [4 ]
机构
[1] Taif Univ, Coll Sci, Dept Phys, POB 11099, At Taif 21944, Saudi Arabia
[2] Southern Fed Univ, Smart Mat Res Inst, Sladkova 178-24, Rostov Na Donu 344090, Russia
[3] Al Azhar Univ, Fac Sci, Phys Dept, PO 71452, Assiut, Egypt
[4] Al Azhar Univ, Fac Sci, Chem Dept, PO 71452, Assiut, Egypt
关键词
UV-visible; Glass-ceramic; SEM; RADIATION SHIELDING PROPERTIES; OPTICAL BASICITY; ELECTRONIC POLARIZABILITY; BORATE GLASSES; SODIUM-BORATE; SILICATE; OXIDE; IONS; IRRADIATION; PARAMETERS;
D O I
10.1007/s13538-021-00928-1
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The conventional technique has been used to prepare a quaternary glass based on the chemical composition 5Al(2)O(3)-(10 + x) Li2O-(70 - x) B2O3-15TiO(2): (0 <= x <= 25) mol.%. The Fourier transform infrared spectrometer spectra were investigated for the structural change of these glasses. Ultraviolet spectroscopic at ambient temperature of the investigated glass system. The optical bandgap and refractive index of these glasses were decreased, while Urbach energy was increased. The polarizability and basicity of these glasses have been established. To demonstrate the influence of titanium oxide on dispersion parameters, these glasses were applied. Under controlled heating, the glass-ceramic was prepared and investigated using X-ray diffraction and mechanical characteristic. Glass-ceramic surface morphology has been examined by scanning electron microscope.
引用
收藏
页码:1237 / 1248
页数:12
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