Design and Synthesis of New Circularly Polarized Thermally Activated Delayed Fluorescence Emitters

被引：313

作者：

Feuillastre, Sophie ^{[1
]}

Pauton, Mathilde ^{[1
]}

Gao, Longhui ^{[1
]}

Desmarchelier, Alaric ^{[1
]}

Riives, Adrian J. ^{[2
]}

Prim, Damien ^{[3
]}

Tondelier, Denis ^{[4
]}

Geffroy, Bernard ^{[4
,5
]}

Muller, Gilles ^{[2
]}

Clavier, Gilles ^{[6
]}

Pieters, Gregory ^{[1
]}

机构：

[1] Univ Paris Saclay, CEA, SCBM, F-91191 Gif Sur Yvette, France

[2] San Jose State Univ, Dept Chem, One Washington Sq, San Jose, CA 95192 USA

[3] Univ Versailles St Quentin en Yvelines, ILV, CNRS, UMR 8180, 45 Ave Etats Unis, F-78035 Versailles, France

[4] Univ Paris Saclay, Ecole Polytech, CNRS, LPICM, F-91128 Palaiseau, France

[5] Univ Paris Saclay, CEA, CNRS, LICSEN,NIMBE, F-91191 Gif Sur Yvette, France

[6] Univ Paris Saclay, CNRS, ENS Cachan, PPSM, F-94235 Cachan, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2016年 / 138卷 / 12期

关键词：

LIGHT-EMITTING-DIODES; ENANTIOSELECTIVE SYNTHESIS; ORGANIC-MOLECULES; LUMINESCENCE; ELECTROLUMINESCENCE; ELLIPSOMETER;

D O I：

10.1021/jacs.6b00850

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This work describes the first thermally activated delayed fluorescence material enabling circularly polarized light emission through chiral perturbation. These new molecular architectures obtained through a scalable one-pot sequential synthetic procedure at room temperature (83% yield) display high quantum yield (up to 74%) and circularly polarized luminescence with an.absolute luminescence dissymmetry factor, vertical bar g(lum)vertical bar, of 1.3 X 10(-3). These chiral molecules have been used as an emissive dopant in an organic light emitting diode exhibiting external quantum efficiency as high as 9.1%.

引用

页码：3990 / 3993

页数：4

共 29 条

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