Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide

被引：13

作者：

Banwell, M ^{[1
]}

Hockless, D

Jarrott, B

Kelly, B

Knill, A

Longmore, R

Simpson, G

机构：

[1] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT 0200, Australia

[2] Monash Univ, Dept Pharmacol, Clayton, Vic 3168, Australia

[3] CSIRO Mol Sci, Clayton, Vic 3169, Australia

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2000年 / 21期

关键词：

D O I：

10.1039/b006759h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The enantiopure dienes 8 and 24, which have been prepared by chemoenzymatic methods, engage in Diels-Alder cycloaddition reactions with maleic and citraconic anhydride to give adducts (e.g. 25-27) embodying the ABC-ring system associated with spinosyns A (1) and D (2).

引用

页码：3555 / 3558

页数：4

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