Cellulose/biochar aerogels with excellent mechanical and thermal insulation properties

被引:52
作者
Lazzari, Lidia K. [1 ]
Perondi, Daniele [2 ]
Zampieri, Vitoria B. [2 ]
Zattera, Ademir J. [2 ]
Santana, Ruth M. C. [1 ]
机构
[1] Univ Fed Rio Grande do Sul, Post Grad Program Min Met & Mat Engn, Porto Alegre, RS, Brazil
[2] Univ Caxias do Sul, Postgrad Program Proc & Technol Engn, Francisco Getulio Vargas St 1130,Bloco 5, Caxias Do Sul, RS, Brazil
关键词
Pinus elliottii cellulose; Biochar; Carbon structure; Aerogel; Thermal insulation; NANOFIBRILLATED CELLULOSE; CARBON AEROGELS; HIGH-STRENGTH; CARBOXYMETHYL CELLULOSE; ABSORPTION PROPERTIES; SILICA AEROGELS; CONDUCTIVITY; FABRICATION; PYROLYSIS; OIL;
D O I
10.1007/s10570-019-02696-3
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
Aiming at investigating the use of alternative materials for the production of thermal insulation and, mainly, to replace the carbon structures (graphene and nanotubes), extensively used in the development of aerogels, the present study had the objective to produce cellulose/biochar aerogels and to evaluate their properties. The aerogels were produced from Pinus elliottii cellulose fibers and biochar produced from these fibers. The materials were characterized in their physical, thermal and mechanical properties. They were extremely light and porous, with a density between 0.01 and 0.027 g cm(-3) and porosity between 93 and 97%. Several percentages of biochars were added to the cellulose suspension (0-100% w/w). The use of 40 wt% biochar provided a 60% increase in the compressive strength of the aerogel in relation to the cellulose aerogel. Besides that, the addition of this carbonaceous structure did not influence significantly the thermal conductivity of the aerogels, which presented a thermal conductivity of 0.021-0.026 W m(-1) K-1. The materials produced in the present research present a great potential to be used as insulators due to the low thermal conductivity found, which was very similar to the thermal conductivity of the air and also of commercial materials such as polyurethane foam and expanded polystyrene.
引用
收藏
页码:9071 / 9083
页数:13
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