Temperature dependence of the crystalline quality of AlN layer grown on sapphire substrates by metalorganic chemical vapor deposition

We studied temperature dependence of crystalline quality of AlN layers at 1050-1250 degrees C with a fine increment step of around 18 degrees C. The AlN layers were grown on c-plane sapphire substrates by metalorganic chemical vapor deposition (MOCVD) and characterized by X-ray diffraction (XRD) omega-scans and atomic force microscopy (AFM). At 1050-1068 degrees C, the templates exhibited poor quality with surface pits and higher XRD (002) and (102) full-width at half-maximum (FWHM) because of insufficient Al atom mobility. At 1086 degrees C, the surface became smooth suggesting sufficient Al atom mobility. Above 1086 degrees C, the (102) FWHM and thus edge dislocation density increased with temperatures which may be attributed to the shorter growth mode transition from three-dimension (3D) to two-dimension (2D). Above 1212 degrees C, surface macro-steps were formed due to the longer diffusion length of Al atoms than the expected step terrace width. The edge dislocation density increased rapidly above 1212 degrees C, indicating this temperature may be a threshold above which the impact of the transition from 3D to 2D is more significant. The (002) FWHM and thus screw dislocation density were insensitive to the temperature change. This study suggests that high quality AlN/sapphire templates may be potentially achieved at temperatures as low as 1086 degrees C which is accessible by most of the Ill nitride MOCVD systems. (C) 2014 Elsevier B.V. All rights reserved.