Polystyrene-supported palladium(II) N,N-dimethylethylenediamine complex: A recyclable catalyst for Suzuki-Miyaura cross-coupling reactions in water

被引：7
|
作者：
Balaswamy, Kodicherla [1 ]
Pullaiah, Perumgani C. [1 ]
Srinivas, Keesara [1 ]
Rao, Mandapati Mohan [1 ]
机构：
[1] CSIR, Indian Inst Chem Technol, I&PC Div, Hyderabad 500607, Andhra Pradesh, India
来源：
INORGANICA CHIMICA ACTA | 2014年 / 423卷
关键词：
Polymer anchored Pd(II) catalyst; Suzuki-Miyaura coupling; Arylboronic acid; Aryl bromide; Aqueous solution; HETEROGENEOUS CATALYST; PD(II) COMPLEX; BASE COMPLEX; SONOGASHIRA; EFFICIENT; RESIN; HECK; ST1571;
D O I：
10.1016/j.ica.2014.07.044
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The polystyrene-supported Pd(II) N,N-dimethylethylenediamine complex was prepared and characterized by various techniques, including Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), atomic absorption spectroscopy (AAS), and thermal analysis (TG-DTA). This heterogeneous Pd(II) catalyst works efficiently for the Suzuki-Miyaura coupling of arylboronic acids with aryl bromides in aqueous medium. The effect of base, and additives for the C-C coupling reactions were reported. Further, the catalyst can be easily recovered quantitatively by simple filtration and reused up to five times without significant loss in its catalytic activity. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：95 / 100
页数：6
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