Polystyrene-supported palladium(II) N,N-dimethylethylenediamine complex: A recyclable catalyst for Suzuki-Miyaura cross-coupling reactions in water

被引：7

作者：

Balaswamy, Kodicherla ^{[1
]}

Pullaiah, Perumgani C. ^{[1
]}

Srinivas, Keesara ^{[1
]}

Rao, Mandapati Mohan ^{[1
]}

机构：

[1] CSIR, Indian Inst Chem Technol, I&PC Div, Hyderabad 500607, Andhra Pradesh, India

来源：

INORGANICA CHIMICA ACTA | 2014年 / 423卷

关键词：

Polymer anchored Pd(II) catalyst; Suzuki-Miyaura coupling; Arylboronic acid; Aryl bromide; Aqueous solution; HETEROGENEOUS CATALYST; PD(II) COMPLEX; BASE COMPLEX; SONOGASHIRA; EFFICIENT; RESIN; HECK; ST1571;

D O I：

10.1016/j.ica.2014.07.044

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The polystyrene-supported Pd(II) N,N-dimethylethylenediamine complex was prepared and characterized by various techniques, including Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), atomic absorption spectroscopy (AAS), and thermal analysis (TG-DTA). This heterogeneous Pd(II) catalyst works efficiently for the Suzuki-Miyaura coupling of arylboronic acids with aryl bromides in aqueous medium. The effect of base, and additives for the C-C coupling reactions were reported. Further, the catalyst can be easily recovered quantitatively by simple filtration and reused up to five times without significant loss in its catalytic activity. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：95 / 100

页数：6

共 31 条

[1]

Ackermann L, 2009, MODERN ARYLATION METHODS, P1

[2]

[Anonymous], 2004, METAL CATALYZED CROS

[3] A novel 1,2,4-triazine-functionalized polystyrene resin-supported Pd(II) complex: A copper- and solvent-free highly efficient catalyst for Sonogashira coupling reactions [J].

Bakherad, Mohammad ;

Bahramian, Bahram ;

Jajarmi, Saeideh .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 749 :405-409

[4] A dithizone-functionalized polystyrene resin-supported Pd(II) complex as an effective catalyst for Suzuki, Heck, and copper-free Sonogashira reactions under aerobic conditions in water [J].

Bakherad, Mohammad ;

Jajarmi, Saeideh .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2013, 370 :152-159

[5] Copper- and solvent-free Sonogashira coupling reactions of aryl halides with terminal alkynes catalyzed by 1-phenyl-1,2-propanedione-2-oxime thiosemi-carbazone-functionalized polystyrene resin supported Pd(II) complex under aerobic conditions [J].

Bakherad, Mohammad ;

Keivanloo, Ali ;

Bahramian, Bahram ;

Jajarmi, Saeedeh .

APPLIED CATALYSIS A-GENERAL, 2010, 390 (1-2) :135-140

[6] Polystyrene-supported Palladium(II) Ethylenediamine Complex: A Recyclable Catalyst for the Syntheses of 2-Benzylimidazo[2,1-b][1,3]benzothiazoles by Sonogashira Reaction [J].

Bakherad, Mohammad ;

Bahramian, Bahram ;

Nasr-Isfahani, Hossein ;

Keivanloo, Ali ;

Sang, Golnaz .

CHINESE JOURNAL OF CHEMISTRY, 2009, 27 (02) :353-358

[7] An improved preparation of mesoporous silica-supported Pd as sustainable catalysts for phosphine-free Suzuki-Miyaura and Heck coupling reactions [J].

Basu, Basudeb ;

Paul, Susmita .

APPLIED ORGANOMETALLIC CHEMISTRY, 2013, 27 (10) :588-594

[8] Palladium catalysts supported on amine-functionalized glycidyl methacrylate gel type terpolymers. Synthesis, characteristics and study of catalytic activity in Suzuki-Miyaura reactions [J].

Bester, Karol ;

Bukowska, Agnieszka ;

Bukowski, Wiktor .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2013, 378 :124-134

[9]

Boren J, 2001, J BIOL CHEM, V276, P37747

[10] Preparation of polymer-supported palladium/N-heterocyclic carbene complex for Suzuki cross-coupling reactions [J].

Byun, JW ;

Lee, YS .

TETRAHEDRON LETTERS, 2004, 45 (09) :1837-1840

← 1 2 3 4 →