Optimization of slow pyrolysis process parameters using a fixed bed reactor for biochar yield from rice husk

被引:122
作者
Vieira, Fabio Roberto [1 ]
Romero Luna, Carlos M. [1 ,2 ]
Arce, Gretta L. A. F. [1 ]
Avila, Ivonete [1 ]
机构
[1] Sao Paulo State Univ Unesp, Sch Engn, Lab Combust & Carbon Capture LC3, Campus Guaratingueta, BR-12516410 Sao Paulo, SP, Brazil
[2] Sao Paulo State Univ Unesp, Campus Itapeva, BR-18409010 Sao Paulo, SP, Brazil
关键词
Slow pyrolysis; Biochar; Rice husk; Fixed bed reactor; Biomass; BIO-OIL PRODUCTION; BIOMASS PYROLYSIS; TEMPERATURE; COMBUSTION; WASTE; CHAR;
D O I
10.1016/j.biombioe.2019.105412
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
A fixed bed reactor has been used to assess the influence of slow pyrolysis process parameters on biochar yield from rice husk. Taguchi's method (L9) was used for such a purpose, which four parameters varied according to three different levels: heating rate (beta) of 5, 10 and 20 degrees C/min; temperature (T) of 300, 400, and 500 degrees C; residence time (t) of 3600, 5400 and 7200 s; rice husk mass (m) of 125, 250, and 500 g. ANOVA were utilized to verify the statistical significance of process parameters. Different physical-chemistry techniques have been performed to assess the energy potential of processing rice husk through thermochemical processes. The results showed that the highest biochar yield (37.71 %wt) was achieved through the following experimental conditions: 500 g of biomass, beta = 20 degrees C/min, T = 300 degrees C, and t = 5400 s. However, the highest heating value (HHV = 23.41 MJ/kg) was obtained by using 125 g of biomass, beta = 10 degrees C/min, T = 500 degrees C, and t = 5400 s. However, optimal conditions for higher fixed carbon content (60.10 %wt) were 500 g of biomass, beta = 5 degrees C/min, T = 500 degrees C, and t = 7200 s. It was 49.05% higher than HHV found for raw rice husk. ANOVA results have revealed that temperature is the most significant parameter for the slow pyrolysis process. Furthermore, Taguchi's method was applied to define the levels of experimental conditions and optimize the process. Energy ratio assessment yielded values ranging between 0.38 and 1.77, which indicates that it is technically feasible to obtain energy gains through the slow pyrolysis of rice husk.
引用
收藏
页数:11
相关论文
共 51 条
[51]   Upgrading of bio-oil from biomass fast pyrolysis in China: A review [J].
Zhang, Le ;
Liu, Ronghou ;
Yin, Renzhan ;
Mei, Yuanfei .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2013, 24 :66-72