Synthesis and Spectroscopic Structural Elucidation of Some Novel Heterobimetallic Complexes of Monoorganotin(IV)

被引：0

作者：

Sharma, Nandu Bala ^{[1
]}

Ghadwal, Rajendra Singh ^{[1
]}

Singh, Anirudh ^{[1
]}

机构：

[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India

来源：

MAIN GROUP METAL CHEMISTRY | 2009年 / 32卷 / 05期

关键词：

HETEROMETALLIC ALKOXIDES; HETERONUCLEAR DERIVATIVES; V-51) CHARACTERIZATION; 1ST SERIES; ALUMINUM; CHEMISTRY; OXOVANADIUM(V); BUTYLTIN(IV); MOIETIES; NMR;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel heterobimetallic organotin(IV) derivatives of the types R'N(CH2CH2O)(2)Sn(R){(OCH2CH2)NR'(OCH2CH2O)M(OCH2CH2)(2)NR'}, and [RSn(OGO) {OV (OGO)}(2)](2) (where R = Bu, R' = H, M = Al 1; R = Bu, R' = Me, M = Al 2, R = Bu, R' = Bu, M = Al 3; R = Bu, R' = Ph, M = Al 4; R = Bu, R' = Me, M = OV 5; R = Bu, R' = Ph, M = OV 6; R = Ph, R' = Me, M = OV 7; R = Ph, R' = Ph, M = OV 8, R = Bu, G = CHMeCH2CMe2 9; R = Bu, G = CMe2CH2CH2CMe2 10; R = Ph, G = CHMeCH2CMe2 11, R = Ph, G = CMe2CH2CH2CMe2 12) have been prepared and characterised by elemental analyses, molecular weight measurements, IR and NMR (H-1, Al-27, V-51 and Sn-119) studies Cryoscopic molecular weight determinations show that complexes 1-8 are monomeric, whereas 9-12 are dimeric.

引用

页码：253 / 262

页数：10

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