Multielemental Characterization of Airborne Particulate Matter Collected in Bucharest and Tokushima by Inductively Coupled Plasma Mass Spectrometry and Inductively Coupled Plasma Atomic Emission Spectrometry

被引:4
作者
Yabutani, Tomoki [1 ]
Nakamoto, Yumi [1 ]
Yamanouchi, Ryoji [1 ]
Thuy, Le Thi Xuan [1 ]
Murai, Kei-ichiro [1 ]
Motonaka, Junko [1 ]
Ogaki, Mitsuharu [1 ]
Dancila, Madelene Anette [2 ]
Stanescu, Rodica [2 ]
Plesca, Marinela [3 ]
机构
[1] Univ Tokushima, Dept Chem Sci & Technol, Inst Sci & Technol, Tokushima 7708506, Japan
[2] Univ Politehn Bucuresti, Fac Ind Chem, Dept Inorgan Technol & Environm Protect, Bucharest 011061, Romania
[3] Reg Environm Protect Agcy Bucharest, Bucharest 060841, Romania
关键词
TRACE-ELEMENTS; AMBIENT AIR; ICP-AES; TOKYO; AEROSOL; SAMPLES; NAGOYA; JAPAN; MS;
D O I
10.2116/analsci.26.395
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Airborne particulate matter (PM) collected in Bucharest (Romania) and Tokushima (Japan) was comprehensively characterized through multielemental analysis by ICP-MS to the PM samples. Prior to an elemental characterization of the sample, a multielemental determination method composed of acid digestion (HClO(4)/HNO(3)/HF or H(2)O(2)/HNO(3)/HF) and inductively coupled plasma mass spectrometry/inductively coupled plasma atomic emission spectrometry (ICP-MS/ICP-AES) was established to analyze a certified reference material of vehicle exhaust matter (NIES No. 8) for verifying the method. As the results, 39 elements in the certified reference material could be determined. They were a good agreement with the certified and reference values for HClO(4)/HNO(3)/HF acid digestion. Chalcophile elements, such as cadmium, antimony, and lead in Bucharest showed higher enrichment factors than those in Tokushima.
引用
收藏
页码:395 / 400
页数:6
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