Efficient and Selective Room-Temperature Gold-Catalyzed Reduction of Nitro Compounds with CO and H2O as the Hydrogen Source

被引：210

作者：

He, Lin ^{[1
]}

Wang, Lu-Cun ^{[1
]}

Sun, Hao ^{[1
]}

Ni, Ji ^{[1
]}

Cao, Yong ^{[1
]}

He, He-Yong ^{[1
]}

Ean, Kang-Nian ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 50期

关键词：

chemoselectivity; gold; nitro compounds; reduction; sustainable chemistry; AEROBIC ALCOHOL OXIDATION; OXIDE-SUPPORTED GOLD; GAS SHIFT REACTION; AROMATIC-AMINES; CHEMOSELECTIVE HYDROGENATION; CO/H2O CONDITIONS; ACTIVE-SITES; WATER; NANOPARTICLES; SIZE;

D O I：

10.1002/anie.200904647

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Chemical equation presented] Taking hydrogen from water: Gold catalysis enabled the selective reduction of nitro compounds under very mild conditions with a combination of H2O and CO as the reductant (see scheme). This environmentally friendly reaction proceeded in high yield and with high chemoselectivity in the presence of a wide range of functional groups © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.

引用

页码：9538 / 9541

页数：4

共 50 条

[41] High turnover and selective Bin-Pd-NCs catalyst for nitro group non-hydrogen reductions in H2O under air conditions: A sustainable and recyclable route to aromatic amines [J].

Xia, Yun-Tao ;

Wang, Xia ;

Su, Ming-Hui ;

Zhou, Jia-Yong ;

Guo, Duo-Xin ;

Zhang, Bin-Peng ;

Sun, Wan-Peng ;

Cui, Chen ;

Yan, Meng ;

Li, Ya-Xin .

JOURNAL OF CATALYSIS, 2024, 437

[42] Room-temperature Synthesis of MnMoO4•H2O Nanorods by the Microemulsion-based Method and Its Photocatalytic Performance [J].

Mi, Yan ;

Huang, Zaiyin ;

Zhou, Zeguang ;

Hu, Feilong ;

Meng, Qiufeng .

8TH CHINA INTERNATIONAL NANOSCIENCE AND TECHNOLOGY SYMPOSIUM (CINSTS09), 2009, 188

[43] Ultrathin nanosheets of molecular sieve SAPO-5: A new photocatalyst for efficient photocatalytic reduction of CO2 with H2O to methane [J].

Zhu, Shuying ;

Liang, Shijing ;

Wang, Ying ;

Zhang, Xiaoyan ;

Li, Fuying ;

Lin, Huaxiang ;

Zhang, Zizhong ;

Wang, Xuxu .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 187 :11-18

[44] Rapid and green reduction of aromatic/aliphatic nitro compounds to amines with NaBH4 and additive Ni2B in H2O [J].

Behzad Zeynizadeh ;

Mehdi Zabihzadeh .

Journal of the Iranian Chemical Society, 2015, 12 :1221-1226

[45] Highly Efficient and Selective Visible-Light Driven CO2-to-CO Conversion by a Co(II) Homogeneous Catalyst in H2O/CH3CN Solution [J].

Liu, Dong-Cheng ;

Huang, Hai-Hua ;

Wang, Jia-Wei ;

Jiang, Long ;

Zhong, Di-Chang ;

Lu, Tong-Bu .

CHEMCATCHEM, 2018, 10 (16) :3435-3440

[46] Room-temperature strategy for networked nonspherical gold nanostructures from Au(III)-[G-2]-CO2H dendrimer complex [J].

Gao, SY ;

Zhang, HJ ;

Liu, XD ;

Wang, XM ;

Ge, LH .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 293 (02) :409-413

[47] Enhanced Photocatalytic Reduction of CO2 on Rutile TiO2/MgAl Layered Double Oxides with H2O Under Ambient Temperature [J].

Chong, Ruifeng ;

Su, Caihong ;

Wang, Zhenzhen ;

Chang, Zhixian ;

Zhang, Ling ;

Li, Deliang .

CATALYSIS LETTERS, 2020, 150 (04) :1061-1071

[48] An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source [J].

Liu, Huan ;

Yang, Da ;

Wang, Dong-Liang ;

Wang, Peng ;

Lu, Yong ;

Vo-Thanh Giang ;

Liu, Ye .

CHEMICAL COMMUNICATIONS, 2018, 54 (57) :7979-7982

[49] Effects of O2, CO2 and H2O on NOx adsorption and selective catalytic reduction over Fe/ZSM-5 [J].

Yang, Terris T. ;

Bi, Hsiaotao T. ;

Cheng, Xingxing .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2011, 102 (1-2) :163-171

[50] Selective reduction of nitroarenes to N-arylhydroxylamines by use of Zn in a CO2–H2O system, promoted by ultrasound [J].

Shijuan Liu ;

Yanhua Wang ;

Xun Yang ;

Jingyang Jiang .

Research on Chemical Intermediates, 2012, 38 :2471-2478

← 1 2 3 4 5 →