Efficient and Selective Room-Temperature Gold-Catalyzed Reduction of Nitro Compounds with CO and H2O as the Hydrogen Source

被引：210

作者：

He, Lin ^{[1
]}

Wang, Lu-Cun ^{[1
]}

Sun, Hao ^{[1
]}

Ni, Ji ^{[1
]}

Cao, Yong ^{[1
]}

He, He-Yong ^{[1
]}

Ean, Kang-Nian ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 50期

关键词：

chemoselectivity; gold; nitro compounds; reduction; sustainable chemistry; AEROBIC ALCOHOL OXIDATION; OXIDE-SUPPORTED GOLD; GAS SHIFT REACTION; AROMATIC-AMINES; CHEMOSELECTIVE HYDROGENATION; CO/H2O CONDITIONS; ACTIVE-SITES; WATER; NANOPARTICLES; SIZE;

D O I：

10.1002/anie.200904647

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Chemical equation presented] Taking hydrogen from water: Gold catalysis enabled the selective reduction of nitro compounds under very mild conditions with a combination of H2O and CO as the reductant (see scheme). This environmentally friendly reaction proceeded in high yield and with high chemoselectivity in the presence of a wide range of functional groups © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.

引用

页码：9538 / 9541

页数：4

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