A simplified synthesis of (+/-)-1,2-diphenyl-1,2-diaminoethane (1) from benzaldehyde and ammonia. Revision of the structures of the long-known intermediates ''hydrobenzamide'' and ''amarine''

被引：61

作者：

Corey, EJ

Kuhnle, FNM

机构：

[1] Dept. of Chem. and Chemical Biology, Harvard University, Cambridge

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 50期

关键词：

D O I：

10.1016/S0040-4039(97)10372-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new pathway for the simple, stereocontrolled and economical synthesis of (+/-)-1 from benzaldehyde is described. The structures of two intermediates (Scheme 1) have been revised to those shown in Scheme 2. (C) 1997 Elsevier Science Ltd.

引用

页码：8631 / 8634

页数：4

共 36 条

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