Crystallization, densification and dielectric properties of CaO-MgO-Al2O3-SiO2 glass with ZrO2 as nucleating agent

被引:37
作者
Hsiang, Hsing-I [1 ]
Yung, Shi-Wen [2 ]
Wang, Chung-Ching [1 ]
机构
[1] Natl Cheng Kung Univ, Particulate Mat Res Ctr, Dept Resources Engn, Tainan 70101, Taiwan
[2] Natl United Univ, Dept Mat Sci & Engn, Miaoli 36003, Taiwan
关键词
Glasses; Dielectric properties; Microstructure; CERAMIC COMPOSITES; LOW-TEMPERATURE; TIO2; MICROSTRUCTURE; ANORTHITE; STRENGTH; DIOPSIDE; KINETICS; BEHAVIOR;
D O I
10.1016/j.materresbull.2014.09.058
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The zirconium oxide effects on the crystallization and dielectric properties of CaO-MgO-Al2O3-SiO2 (CMAS) glass were investigated. The results showed that phyllosiloxide and anorthite crystallites were observed in sequence during sintering. For glass added with 8 wt% ZrO2, homogeneously dispersed tetragonal ZrO2 crystallites were observed at 850 degrees C. The as-prepared CMAS glass-ceramics exhibited a dielectric constant of about 6-7 and a dielectric loss below 0.005 at 100 MHz. The dielectric properties of CMAS glass with 8 wt% ZrO2 sintered at 850 degrees C show a low dielectric constant of 6.65 and a dielectric loss tangent of about 2.5 x 10(-3), which provides a promising candidate for LTCC applications. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:730 / 737
页数:8
相关论文
共 37 条
[1]  
[Anonymous], 2009, INT J APPL CERAM TEC, DOI DOI 10.1111/J.1744-7402.2008.02255.X
[2]   Integration concepts for the fabrication of LTCC structures [J].
Baker, A ;
Lanagan, M ;
Randall, C ;
Semouchkina, E ;
Semouchkin, G ;
Rajah, KZ ;
Eitel, R ;
Rajab, KZ ;
Mittra, R ;
Rhee, S ;
Geggier, P ;
Duschl, C ;
Fuhr, G .
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2005, 2 (06) :514-520
[3]   Crystallization and sintering characteristics of CaO-Al2O3-SiO2 glasses in the presence of TiO2, CaF2 and ZrO2 [J].
Banijamali, S. ;
Yekta, B. Eftekhari ;
Rezaie, H. R. ;
Marghussian, V. K. .
THERMOCHIMICA ACTA, 2009, 488 (1-2) :60-65
[4]   Crystallization kinetics and mechanism of low-dielectric, low-temperature, cofirable CaO-B2O3-SiO2 glass-ceramics [J].
Chang, CR ;
Jean, JH .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1999, 82 (07) :1725-1732
[5]   Sintering, crystallization, and properties of CaO doped cordierite-based glass-ceramics [J].
Chen, Guo-hua .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 455 (1-2) :298-302
[6]  
Cheng KG, 1999, J AM CERAM SOC, V82, P1212, DOI 10.1111/j.1151-2916.1999.tb01898.x
[7]   KINETIC PROCESSES INVOLVED IN THE SINTERING AND CRYSTALLIZATION OF GLASS POWDERS [J].
CLARK, TJ ;
REED, JS .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1986, 69 (11) :837-846
[8]   Zirconia nucleating agent on microstructural and electrical properties of a CaMgSi2O6 diopside glass-ceramic for microwave dielectrics [J].
Feng, Kuei-Chih ;
Chou, Chen-Chia ;
Chu, Li-Wen ;
Chen, Haydn .
MATERIALS RESEARCH BULLETIN, 2012, 47 (10) :2851-2855
[9]   Effects of nucleating agents on crystallization and microstructure of fluorophlogopite mica-containing glass-ceramics [J].
Garai, M. ;
Sasmal, N. ;
Molla, A. R. ;
Singh, S. P. ;
Tarafder, A. ;
Karmakar, B. .
JOURNAL OF MATERIALS SCIENCE, 2014, 49 (04) :1612-1623
[10]   Sintering behavior and mechanical properties of mica-diopside glass-ceramic composites reinforced by nano and micro-sized zirconia particles [J].
Ghaffari, M. ;
Alizadeh, P. ;
Rahimipour, M. R. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2012, 358 (23) :3304-3311