An efficient, green and scale-up synthesis of amides from esters and amines catalyzed by Ru-MACHO catalyst under mild conditions

被引：26
作者：
Han, Qian [1 ]
Xiong, Xingquan [1 ]
Li, Sizhong [1 ]
机构：
[1] Univ Huaqiao, Coll Mat Sci & Engn, Xiamen 361021, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2015年 / 58卷
基金：
中国国家自然科学基金;
关键词：
Amides; Esters; Amines; Ru-MACHO; Green synthesis; ALCOHOLS; COMPLEXES; DEHYDROGENATION; AMINOLYSIS; HYDROGEN;
D O I：
10.1016/j.catcom.2014.08.036
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An efficient, green and scale-up synthesis of amides from esters and amines has been developed using Ru-MACHO as a readily available catalyst. A diverse range of amides were obtained in moderate to excellent yields (55-98%). Furthermore, when the scale of the amidation reaction was increased to 240.0 mmol, the desired amide still could be obtained in high yield (48.2 g of N-benzylbenzamide, 95%). (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：85 / 88
页数：4
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