Manipulation of electronic structure via supporting ligands: a charge disproportionate model within the linear metal framework of asymmetric nickel string [Ni7(phdptrany)4Cl](PF6)

被引:14
作者
Hua, Shao-An [1 ]
Huang, Gin-Chen [1 ]
Liu, Isiah Po-Chun [1 ,2 ]
Kuo, Jau-Huei [1 ]
Jiang, Ching-Hong [1 ]
Chiu, Chien-Lan [3 ]
Yeh, Chen-Yu [3 ]
Lee, Gene-Hsiang [1 ]
Peng, Shie-Ming [1 ,2 ]
机构
[1] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
[2] Acad Sinica, Inst Chem, Taipei 115, Taiwan
[3] Natl Chung Hsing Univ, Dept Chem, Taichung 40227, Taiwan
关键词
NEW-GENERATION; COMPLEXES; CHAINS; DELOCALIZATION; MAGNETISM; WIRES;
D O I
10.1039/b926315b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This paper describes the synthesis and physical properties of an uniquely asymmetric heptanickel string complex exhibiting a charge disproportionate model along the linear nickel framework.
引用
收藏
页码:5018 / 5020
页数:3
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